The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Efficient Electrochemical Nitrate Reduction to Ammonia with Copper‐Supported Rhodium Cluster and Single‐Atom Catalysts
Open accessAbstract
The electrochemical nitrate reduction reaction (NITRR) provides a promising solution for restoring the imbalance in the global nitrogen cycle while enabling a sustainable and decentralized route to source ammonia. Here, we demonstrate a novel electrocatalyst for NITRR consisting of Rh clusters and single‐atoms dispersed onto Cu nanowires (NWs), which delivers a partial current density of 162 mA cm−2 for NH 3 production and a Faradaic efficiency (FE) of 93 % at −0.2 V vs. RHE. The highest ammonia yield rate reached a record value of 1.27 mmol h−1 cm−2. Detailed investigations by electron paramagnetic resonance, in situ infrared spectroscopy, differential electrochemical mass spectrometry and density functional theory modeling suggest that the high activity originates from the synergistic catalytic cooperation between Rh and Cu sites, whereby adsorbed hydrogen on Rh site transfers to vicinal *NO intermediate species adsorbed on Cu promoting the hydrogenation and ammonia formation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Zhu, L., Lin, H., Li, Y., Liao, F., Lifshitz, Y., Sheng, M., Lee, S.-T., & Shao, M. (2016) · Nature Communications · doi:10.1038/ncomms12272 · Cited by 351
Cited by
Alloying of Cu with Ru Enabling the Relay Catalysis for Reduction of Nitrate to Ammonia
Gao, W., Xie, K., Xie, J., Wang, X., Zhang, H., Chen, S., Wang, H., Li, Z., & Li, C. (2023) · Advanced Materials · doi:10.1002/adma.202202952 · Cited by 532
Bai, L., Franco, F., Timoshenko, J., Rettenmaier, C., Scholten, F., Jeon, H. S., Yoon, A., Rüscher, M., Herzog, A., Haase, F. T., et al. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c13288 · Cited by 473
Self-citationPulsed Nitrate-to-Ammonia Electroreduction Facilitated by Tandem Catalysis of Nitrite Intermediates
Li, P., Li, R., Liu, Y., Xie, M., Jin, Z., & Yu, G. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c00334 · Cited by 466
Zhou, J., Wen, M., Huang, R., Wu, Q., Luo, Y., Tian, Y., Wei, G., & Fu, Y. (2023) · Energy & Environmental Science · doi:10.1039/d2ee04095f · Cited by 398
Li, X., Shen, P., Li, X., Ma, D., & Chu, K. (2023) · ACS Nano · doi:10.1021/acsnano.2c07911 · Cited by 369
Metadata
- Authors
- Liu, H., Lang, X., Zhu, C., Timoshenko, J., Rüscher, M., Bai, L., Guijarro, N., Yin, H., Peng, Y., Li, J., Liu, Z., Wang, W., Cuenya, B. R., & Luo, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-04-05
- Volume
- 61
- Issue
- 23
- Pages
- e202202556-e202202556
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4220843414
- Cited by
- 596
- References
- 1
- FWCI
- 22.72
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Efficient Electrochemical Nitrate Reduction to Ammonia with Copper‐Supported Rhodium Cluster and Single‐Atom Catalysts. https://app.cochat.ai/papers/10.1002/anie.202202556
- The paper
- Liu, H., Lang, X., Zhu, C., Timoshenko, J., Rüscher, M., Bai, L., Guijarro, N., Yin, H., Peng, Y., Li, J., Liu, Z., Wang, W., Cuenya, B. R., & Luo, J. (2022). Efficient Electrochemical Nitrate Reduction to Ammonia with Copper‐Supported Rhodium Cluster and Single‐Atom Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202202556
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
