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Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction

Zhang, Zedong, Zhu, Jiexin, Chen, Shenghua, Sun, Wenming, Wang, Dingsheng·2023·Angewandte Chemie International Edition

Abstract

Precise design and tuning of the micro‐atomic structure of single atom catalysts (SACs) can help efficiently adapt complex catalytic systems. Herein, we inventively found that when the active center of the main group element gallium (Ga) is downsized to the atomic level, whose characteristic has significant differences from conventional bulk and rigid Ga catalysts. The Ga SACs with a P, S atomic coordination environment display specific flow properties, showing CO products with FE of ≈92 % at −0.3 V vs. RHE in electrochemical CO 2 reduction (CO 2 RR). Theoretical simulations demonstrate that the adaptive dynamic transition of Ga optimizes the adsorption energy of the *COOH intermediate and renews the active sites in time, leading to excellent CO 2 RR selectivity and stability. This liquid single atom catalysts system with dynamic interfaces lays the foundation for future exploration of synthesis and catalysis.

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Metadata

Authors
Zhang, Z., Zhu, J., Chen, S., Sun, W., & Wang, D.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2022-12-13
Volume
62
Issue
3
Pages
e202215136-e202215136
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W4309367996
Cited by
215
References
1
FWCI
8.37
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction. https://app.cochat.ai/papers/10.1002/anie.202215136
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Zhang, Z., Zhu, J., Chen, S., Sun, W., & Wang, D. (2023). Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202215136

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