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Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction
Abstract
Precise design and tuning of the micro‐atomic structure of single atom catalysts (SACs) can help efficiently adapt complex catalytic systems. Herein, we inventively found that when the active center of the main group element gallium (Ga) is downsized to the atomic level, whose characteristic has significant differences from conventional bulk and rigid Ga catalysts. The Ga SACs with a P, S atomic coordination environment display specific flow properties, showing CO products with FE of ≈92 % at −0.3 V vs. RHE in electrochemical CO 2 reduction (CO 2 RR). Theoretical simulations demonstrate that the adaptive dynamic transition of Ga optimizes the adsorption energy of the *COOH intermediate and renews the active sites in time, leading to excellent CO 2 RR selectivity and stability. This liquid single atom catalysts system with dynamic interfaces lays the foundation for future exploration of synthesis and catalysis.
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Cites
Role of oxygen-bound reaction intermediates in selective electrochemical CO 2 reduction
Zhi, X., Vasileff, A., Zheng, Y., Jiao, Y., & Qiao, S.-Z. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00740h · Cited by 149
Cited by
Defect engineering of two-dimensional materials for advanced energy conversion and storage
Liu, F., & Fan, Z. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00931e · Cited by 417
Microenvironment Engineering of Single/Dual‐Atom Catalysts for Electrocatalytic Application
Gao, Y., Liu, B., & Wang, D. (2023) · Advanced Materials · doi:10.1002/adma.202209654 · Cited by 319
Self-citationWang, L., Ma, M., Zhang, C., Chang, H., Zhang, Y., Li, L., Chen, H., & Peng, S. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202317220 · Cited by 125
Metadata
- Authors
- Zhang, Z., Zhu, J., Chen, S., Sun, W., & Wang, D.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-12-13
- Volume
- 62
- Issue
- 3
- Pages
- e202215136-e202215136
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4309367996
- Cited by
- 215
- References
- 1
- FWCI
- 8.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, Z., Zhu, J., Chen, S., Sun, W., & Wang, D. (2023). Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202215136
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