The DOI matches its Crossref record; 60 of the 60 references it cites were found in a registry or an index.
Constructing Built‐in Electric Field in Heterogeneous Nanowire Arrays for Efficient Overall Water Electrolysis
Open accessAbstract
Efficient bifunctional electrocatalysts for hydrogen and oxygen evolution reactions are key to water electrolysis. Herein, we report a built‐in electric field (BEF) strategy to fabricate heterogeneous nickel phosphide‐cobalt nanowire arrays grown on carbon fiber paper (Ni 2 P‐CoCH/CFP) with large work function difference (ΔΦ) as bifunctional electrocatalysts for overall water splitting. Impressively, Ni 2 P‐CoCH/CFP exhibits a remarkable catalytic activity for hydrogen and oxygen evolution reactions to obtain 10 mA cm−2, respectively. Moreover, the assembled lab‐scale electrolyzer driven by an AAA battery delivers excellent stability after 50 h electrocatalysis with a 100 % faradic efficiency. Computational calculations combining with experiments reveal the interface‐induced electric field effect facilitates asymmetrical charge distributions, thereby regulating the adsorption/desorption of the intermediates during reactions. This work offers an avenue to rationally design high‐performance heterogeneous electrocatalysts.
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Citations
Cites
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Huang, Z.-F., Song, J., Du, Y., Xi, S., Dou, S., Nsanzimana, J. M. V., Wang, C., Xu, Z. J., & Wang, X. (2019) · Nature Energy · doi:10.1038/s41560-019-0355-9 · Cited by 1,858
High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting
Yu, F., Zhou, H., Huang, Y., Sun, J., Qin, F., Bao, J., Goddard, W. A., Chen, S., & Ren, Z. (2018) · Nature Communications · doi:10.1038/s41467-018-04746-z · Cited by 1,165
Liang, C., Zou, P., Nairan, A., Zhang, Y., Liu, J., Liu, K., Hu, S., Kang, F., Fan, H. J., & Yang, C. (2020) · Energy & Environmental Science · doi:10.1039/c9ee02388g · Cited by 1,055
Zhou, K. L., Wang, Z., Han, C. B., Ke, X., Wang, C., Jin, Y., Zhang, Q., Liu, J., Wang, H., & Yan, H. (2021) · Nature Communications · doi:10.1038/s41467-021-24079-8 · Cited by 765
Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide
Suryanto, B. H. R., Wang, Y., Hocking, R. K., Adamson, W., & Zhao, C. (2019) · Nature Communications · doi:10.1038/s41467-019-13415-8 · Cited by 740
Luo, Y., Tang, L., Khan, U., Yu, Q., Cheng, H.-M., Zou, X., & Liu, B. (2019) · Nature Communications · doi:10.1038/s41467-018-07792-9 · Cited by 713
Self-citationWu, L., Yu, L., Zhang, F., McElhenny, B., Luo, D., Karim, A., Chen, S., & Ren, Z. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202006484 · Cited by 690
Yang, G., Jiao, Y., Yan, H., Xie, Y., Wu, A., Dong, X., Guo, D., Tian, C., & Fu, H. (2020) · Advanced Materials · doi:10.1002/adma.202000455 · Cited by 633
A fundamental viewpoint on the hydrogen spillover phenomenon of electrocatalytic hydrogen evolution
Li, J., Hu, J., Zhang, M., Gou, W., Zhang, S., Chen, Z., Qu, Y., & Ma, Y. (2021) · Nature Communications · doi:10.1038/s41467-021-23750-4 · Cited by 633
Self-citation
Cited by
Gong, Z., Liu, J., Yan, M., Gong, H., Ye, G., & Fei, H. (2023) · ACS Nano · doi:10.1021/acsnano.3c05749 · Cited by 98
Metadata
- Authors
- Zhang, S., Tan, C., Yan, R., Zou, X., Hu, F., Mi, Y., Yan, C., & Zhao, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2023-05-17
- Volume
- 62
- Issue
- 26
- Pages
- e202302795-e202302795
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4365444108
- Cited by
- 369
- References
- 60
- FWCI
- 17.27
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Zhang, S., Tan, C., Yan, R., Zou, X., Hu, F., Mi, Y., Yan, C., & Zhao, S. (2023). Constructing Built‐in Electric Field in Heterogeneous Nanowire Arrays for Efficient Overall Water Electrolysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202302795
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