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Kinetic analysis of thermogravimetric data
Abstract
Thermogravimetric data are generally more extensive than are comparable isothermal aging data, and therefore afford preliminary kinetic information in greater abundance. The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics. Application of the analytical procedure to the thermogram for the zero-order volatilization of octamethylcyclotetrasiloxane yielded an estimate of 11.65 kcal./mole as the average heat of vaporization in the temperature range of 80 to 145°C. The apparent activation energy for the first-order pyrolytic volatilization of 200-mg. samples of pulverized polytetrafluoroethylene was estimated to be 66 to 68 kcal./mole in the temperature range of 520 to 610°C.
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Citations
Cited by
Kinetic Parameters from Thermogravimetric Data
COATS, A. W., & REDFERN, J. P. (1964) · Nature · doi:10.1038/201068a0 · Cited by 6,930
The ‘Temperature Integral’ — Its use and abuse
Flynn, J. H. (1997) · Thermochimica Acta · doi:10.1016/s0040-6031(97)00046-4 · Cited by 470
Khayyam, H., Jazar, R. N., Nunna, S., Golkarnarenji, G., Badii, K., Fakhrhoseini, S. M., Kumar, S., & Naebe, M. (2020) · Progress in Materials Science · doi:10.1016/j.pmatsci.2019.100575 · Cited by 325
Khawam, A., & Flanagan, D. R. (2006) · Journal of Pharmaceutical Sciences · doi:10.1002/jps.20559 · Cited by 320
The kinetic analysis of the pyrolysis of agricultural residue under non-isothermal conditions
Gai, C., Dong, Y., & Zhang, T. (2013) · Bioresource Technology · doi:10.1016/j.biortech.2012.09.089 · Cited by 286
Metadata
- Authors
- Doyle, C. D.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 1961-05
- Volume
- 5
- Issue
- 15
- Pages
- 285-292
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2102384177
- Cited by
- 1,357
- References
- 0
- FWCI
- 8.76
- Type
- journal article
- Language
- en
- Open access
- closed
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