The entanglement plateau in the dynamic modulus of rubbery styrene–diene block copolymers. Significance to pressure-sensitive adhesive formulations
Abstract
Styrene–diene (butadiene or isoprene) block copolymers of the SDS or $ ({\rm SD\rlap{--} )} $ type exhibit a plateau in the dynamic storage modulus located between the glass transitions of the polydiene and polystyrene domains. When the polydiene is the continuous phase, the height of this plateau can be estimated with good success from the entanglement spacing molecular weight of the polydiene and the filler effect of the polystyrene domains. The effect of introduction of a center block-compatible diluent can also be calculated, although the simple procedure used here tends to underestimate the plasticizer effect, particularly at high diluent concentration. Nevertheless, the calculation furnishes a useful criterion of compatibility of the polydiene center blocks and low molecular weight resins used commonly as tackifiers in pressure-sensitive adhesives. Center block compatibility is essential for the development of tack in these compositions.
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The high entanglement molar mass polymers Pδ5, poly(menthide), and poly(ε-decalactone) have lower modulus.
“The lower modulus of the high entanglement molar mass polymers (e.g., P δ 5 , poly(menthide), and poly( ε -decalactone)) makes them attractive for use in pressure-sensitive adhesives. 9,80 -83”
From Aliphatic Polyester Block Polymer Design (2016) · cites this paper as [83]
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- Authors
- Kraus, G., & Rollmann, K. W.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 1977-12
- Volume
- 21
- Issue
- 12
- Pages
- 3311-3318
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2065158352
- Cited by
- 67
- References
- 0
- Citations by year
- 2026: 2 · 2025: 2 · 2022: 1 · 2021: 2 · 2020: 1 · 2019: 1 · 2017: 1 · 2016: 1 · 2014: 1 · 2013: 1
- FWCI
- 0.48
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Polymer Science (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- storage modulus, 1,3-butadiene, isoprene, filler effect, horse equipment, pressure-sensitive adhesives, plasticizer effect
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