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Criteria for rheological compatibility of polymer blends
Abstract
Criteria for rheological compatibility of polymer blends are suggested. The criteria suggested make use of plots of first normal stress difference (N1) against shear stress (σ 12), and of storage modulus (G′) against loss modulus (G″). Compatible blend systems considered are (1) blends of two different grades of low‐density polyethylene, (2) blends of poly(vinylidene fluoride) and poly(methyl methacrylate), (3) blends of poly(2,6‐dimethyl‐1,4‐phenylene oxide) and polystyrene, and (4) blends of poly(styrene‐co‐acrylonitrile) and poly(styrene‐co‐maleic anhyride). And incompatible blend systems considered are (1) blends of nylon 6 and poly(ethylene‐co‐vinyl acetate) and (2) blends of nylon 6 and an ethylene‐based multifunctional polymer. It has been found that plots of N1 vs. σ 12 and G′ vs. G″ give (a) temperature‐independent correlations for both compatible and incompatible blend systems; (b) composition‐independent correlations for compatible blends; (c) composition‐dependent correlations for incompatible blends.
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Cited by
POSS Polymers: Physical Properties and Biomaterials Applications
Wu, J., & Mather, P. T. (2009) · Polymer Reviews · doi:10.1080/15583720802656237 · Cited by 411
Rheological and Viscoelastic Behavior of HDPE/Octamethyl-POSS Nanocomposites
Joshi, M., Butola, B. S., Simon, G., & Kukaleva, N. (2006) · Macromolecules · doi:10.1021/ma051357w · Cited by 270
Hu, J., Wang, W., Liu, X., Du, Y., Zhang, H., Duan, R., Bian, X., Liu, Y., & Chen, X. (2024) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2024.136161 · Cited by 8
Metadata
- Authors
- Han, C. D., & Chuang, H.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 1985-11
- Volume
- 30
- Issue
- 11
- Pages
- 4431-4454
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2118241232
- Cited by
- 174
- References
- 0
- FWCI
- 2.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- Han, C. D., & Chuang, H. (1985). Criteria for rheological compatibility of polymer blends. Journal of Applied Polymer Science. https://doi.org/10.1002/app.1985.070301118
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