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Mechanical properties of LDPE/granular starch composites
Abstract
The mechanical properties of composites of granular starch and low density polyethylene (PE) have been studied as functions of starch volume fraction ϕ, granule size, and presence of compatibilizer. Property–volume fraction relationships were interpreted using various theories of composite properties. The dependence of elongation (ϵ ∼ ϕ 1/3) and tensile strength (σ ∼ ϕ 2/3) agree with theoretical predictions, although the proportionality constants are less negative than theoretical values. The addition of compatibilzer (ethylene‐co‐acrylic acid copolymer, EAA) did not significantly affect the elongation or tensile strength, but significantly increased the composite tensile modulus. The cornstarch/PE moduli could be described by the Kerner or Halpin‐Tsai equations. Analysis of the composite moduli data using the Halpin‐Tsai equation allowed the estimation of the modulus of granular starch. The value obtained, 15 GPa, is considerably greater than most unfilled synthetic polymers of commercial importance, but significantly lower than the modulus of cellulose. It is also greater than a previously reported value of 2.7 GPa. © 1994 John Wiley & Sons, Inc.
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Citations
Cited by
Vroman, I., & Tighzert, L. (2009) · Materials · doi:10.3390/ma2020307 · Cited by 1,355
Thermal processing of starch-based polymers
Liu, H., Xie, F., Yu, L., Chen, L., & Li, L. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.07.001 · Cited by 817
Mechanical Properties of Poly(lactic acid)/Starch Composites Compatibilized by Maleic Anhydride
Zhang, J.-F., & Sun, X. (2004) · Biomacromolecules · doi:10.1021/bm0400022 · Cited by 494
Improvement of starch film performances using cellulose microfibrils
Dufresne, A., & Vignon, M. R. (1998) · Macromolecules · doi:10.1021/ma971532b · Cited by 409
High performance LDPE/thermoplastic starch blends: a sustainable alternative to pure polyethylene
Rodriguez-Gonzalez, F. J., Ramsay, B. A., & Favis, B. D. (2003) · Polymer · doi:10.1016/s0032-3861(02)00907-2 · Cited by 260
Metadata
- Authors
- Willett, J. L.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 1994-12-12
- Volume
- 54
- Issue
- 11
- Pages
- 1685-1695
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2101022411
- Cited by
- 210
- References
- 0
- FWCI
- 2.53
- Type
- journal article
- Language
- en
- Open access
- closed
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