The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Strengthening blends of poly(lactic acid) and starch with methylenediphenyl diisocyanate
Abstract
Poly(lactic acid) (PLA) is a biodegradable polymer, but its applications are limited by its high cost. Blending granular starch with PLA reduces the cost, but the blend has poor strength properties. In this study, a 55/45 (w/w) mixture of PLA (weight‐average molecular weight = 120,000 Da) and dried wheat starch was blended thermally in an intensive mixer with or without a low level of methylenediphenyl diisocyanate (MDI). Blends with MDI had enhanced mechanical properties that could be explained by the in situ formation of a block copolymer acting as a compatibilizer. Scanning electron micrographs showed reduced interfacial tension between the two phases. The presence of MDI also enhanced the mechanical properties of the blend at temperatures above the glass‐transition temperature. Water uptakes by the PLA/starch blends with and without MDI did not differ. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1761–1767, 2001
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Cites
Fischer, E. W., Sterzel, H. J., & Wegner, G. (1973) · Kolloid-Zeitschrift und Zeitschrift für Polymere · doi:10.1007/bf01498927 · Cited by 1,704
Large-scale production, properties and commercial applications of polylactic acid polymers
Lunt, J. (1998) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(97)00148-1 · Cited by 1,366
Biodegradable blends and composites of polycaprolactone and starch derivatives
Koenig, M. F., & Huang, S. J. (1995) · Polymer · doi:10.1016/0032-3861(95)90934-t · Cited by 336
Ajioka, M., Enomoto, K., Suzuki, K., & Yamaguchi, A. (1995) · Journal of Environmental Polymer Degradation · doi:10.1007/bf02068677 · Cited by 322
Water vapor permeability of biodegradable polymers
Shogren, R. (1997) · Journal of environmental polymer degradation · doi:10.1007/bf02763592 · Cited by 287
Ajioka, M., Enomoto, K., Suzuki, K., & Yamaguchi, A. (1995) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.68.2125 · Cited by 245
Cited by
Polymer blends and composites from renewable resources
Yu, L., Dean, K., & Li, L. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.03.002 · Cited by 2,107
Poly (lactic acid) blends: Processing, properties and applications
Nofar, M., Sacligil, D., Carreau, P. J., Kamal, M. R., & Heuzey, M.-C. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2018.12.002 · Cited by 780
Polylactic acid blends: The future of green, light and tough
Hamad, K., Kaseem, M., Ayyoob, M., Joo, J., & Deri, F. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.07.001 · Cited by 640
Mechanical Properties of Poly(lactic acid)/Starch Composites Compatibilized by Maleic Anhydride
Zhang, J.-F., & Sun, X. (2004) · Biomacromolecules · doi:10.1021/bm0400022 · Cited by 494
Self-citationHu, R., & Lim, J.-K. (2007) · Journal of Composite Materials · doi:10.1177/0021998306069878 · Cited by 334
Metadata
- Authors
- Wang, H., Sun, X., & Seib, P.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 2001-09-05
- Volume
- 82
- Issue
- 7
- Pages
- 1761-1767
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W1999187510
- Cited by
- 279
- References
- 6
- FWCI
- 2.74
- Type
- journal article
- Language
- en
- Open access
- closed
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