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Cited by 410

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Shape‐Dependent Catalytic Activity of Silver Nanoparticles for the Oxidation of Styrene

Xu, Run, Wang, Dingsheng, Zhang, Jiatao, Li, Yadong·2006·Chemistry – An Asian Journal

Abstract

Metal nanoparticles with different shapes have different crystallographic faces. It is therefore of interest to study the effect of the shape of metal nanoparticles on their catalytic activity in various organic and inorganic reactions. Truncated triangular silver nanoplates with well‐defined planes were synthesized by a simple solvothermal approach. The activity of these truncated triangular silver nanoparticles was compared with that of cubic and near‐spherical silver nanoparticles in the oxidation of styrene in colloidal solution. It was found that the crystal faces of silver nanoparticles play an essential role in determining the catalytic oxidation properties. The silver nanocubes had the {100} crystal faces as the basal plane, whereas truncated triangular nanoplates and near‐spherical nanoparticles predominantly exposed the most‐stable {111} crystal faces. As a result, the rate of the reaction over the nanocubes was more than 14 times higher than that on nanoplates and four times higher than that on near‐spherical nanoparticles.

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Metadata

Authors
Xu, R., Wang, D., Zhang, J., & Li, Y.
Venue
Chemistry – An Asian Journal
Publisher
Wiley
Published
2006-12-07
Volume
1
Issue
6
Pages
888-893
ISSN
  • 1861-471X (ISSN-L)
  • 1861-4728
OpenAlex
W1979140965
Cited by
410
References
2
FWCI
4.37
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Shape‐Dependent Catalytic Activity of Silver Nanoparticles for the Oxidation of Styrene. https://app.cochat.ai/papers/10.1002/asia.200600260
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Xu, R., Wang, D., Zhang, J., & Li, Y. (2006). Shape‐Dependent Catalytic Activity of Silver Nanoparticles for the Oxidation of Styrene. Chemistry – An Asian Journal. https://doi.org/10.1002/asia.200600260

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