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An Evaluation of UiO‐66 for Gas‐Based Applications

Wiersum, Andrew D., Soubeyrand‐Lenoir, Estelle, Yang, Qingyuan, Moulin, Beatrice, Guillerm, Vincent, Yahia, Mouna Ben, Bourrelly, Sandrine, Vimont, Alexandre, Miller, Stuart, Vagner, Christelle, Daturi, Marco, Clet, Guillaume, Serre, Christian, Maurin, Guillaume, Llewellyn, Philip L.·2011·Chemistry – An Asian Journal

Abstract

In addition to its high thermal stability, repetitive hydration/dehydration tests have revealed that the porous zirconium terephthalate UiO‐66 switches reversibly between its dehydroxylated and hydroxylated versions. The structure of its dehydroxylated form has thus been elucidated by coupling molecular simulations and X‐ray powder diffraction data. Infrared measurements have shown that relatively weak acid sites are available while microcalorimetry combined with Monte Carlo simulations emphasize moderate interactions between the UiO‐66 surface and a wide range of guest molecules including CH 4, CO, and CO 2. These properties, in conjunction with its significant adsorption capacity, make UiO‐66 of interest for its further evaluation for CO 2 recovery in industrial applications. This global approach suggests a strategy for the evaluation of metal–organic frameworks for gas‐based applications.

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Metadata

Authors
Wiersum, A. D., Soubeyrand‐Lenoir, E., Yang, Q., Moulin, B., Guillerm, V., Yahia, M. B., Bourrelly, S., Vimont, A., Miller, S., Vagner, C., Daturi, M., Clet, G., Serre, C., Maurin, G., & Llewellyn, P. L.
Venue
Chemistry – An Asian Journal
Publisher
Wiley
Published
2011-09-28
Volume
6
Issue
12
Pages
3270-3280
ISSN
  • 1861-471X (ISSN-L)
  • 1861-4728
OpenAlex
W2129933386
Cited by
240
References
3
FWCI
9.84
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: An Evaluation of UiO‐66 for Gas‐Based Applications. https://app.cochat.ai/papers/10.1002/asia.201100201
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Wiersum, A. D., Soubeyrand‐Lenoir, E., Yang, Q., Moulin, B., Guillerm, V., Yahia, M. B., Bourrelly, S., Vimont, A., Miller, S., Vagner, C., Daturi, M., Clet, G., Serre, C., Maurin, G., & Llewellyn, P. L. (2011). An Evaluation of UiO‐66 for Gas‐Based Applications. Chemistry – An Asian Journal. https://doi.org/10.1002/asia.201100201

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