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A Microdynamic Model of Electrolyte Solutions as Derived from Nuclear Magnetic Relaxation and Self‐Diffusion Data
Abstract
Experimental data of the proton relaxation rate in aqueous solutions of alkali and alkaline earth halides at four different temperatures (0, 25, 50, 80 °C) are reported. A number of measured self‐diffusion coefficients of water in electrolyte solutions at various temperatures are also given. From these experimental data models of the electrolyte solutions are derived which are characterized by certain hydration numbers, reorientational correlation times for the water molecules, translational jumping times, and by the activation energies connected with the respective microdynamic processes.
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Cited by
Confinement or the Nature of the Interface? Dynamics of Nanoscopic Water
Moilanen, D. E., Levinger, N. E., Spry, D. B., & Fayer, M. D. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073977d · Cited by 259
A Diffusive Anomaly of Water in Aqueous Sodium Chloride Solutions at Low Temperatures
Kim, J. S., & Yethiraj, A. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp076710+ · Cited by 41
Metadata
- Authors
- Endom, L., Hertz, H. G., Thül, B., & Zeidler, M. D.
- Venue
- Berichte der Bunsengesellschaft für physikalische Chemie
- Publisher
- Wiley
- Published
- 1967-11
- Volume
- 71
- Issue
- 9-10
- Pages
- 1008-1031
- ISSN
- 0005-9021 (ISSN-L)
- OpenAlex
- W1577152819
- Cited by
- 206
- References
- 0
- FWCI
- 5.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A Microdynamic Model of Electrolyte Solutions as Derived from Nuclear Magnetic Relaxation and Self‐Diffusion Data. https://app.cochat.ai/papers/10.1002/bbpc.19670710907
- The paper
- Endom, L., Hertz, H. G., Thül, B., & Zeidler, M. D. (1967). A Microdynamic Model of Electrolyte Solutions as Derived from Nuclear Magnetic Relaxation and Self‐Diffusion Data. Berichte der Bunsengesellschaft für physikalische Chemie. https://doi.org/10.1002/bbpc.19670710907
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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