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Oxozirconium Methacrylate Clusters: Zr6(OH)4O4(OMc)12 and Zr4O2(OMc)12 (OMc = Methacrylate)
Abstract
The crystalline oxozirconium methacrylate clusters Zr 6(O‐H)4 O 4(OMc)12 and Zr 4 O 2(OMc)12 were obtained by reaction of Zr(O n Pr)4 with an excess of methacrylic acid and analysed by X‐ray diffraction. The oxide and hydroxide groups are in a μ 3‐ bridging mode in both structures, and the methacrylate ligands are chelating or bridging. The zirconium atoms in Zr 6(OH)4 O 4(OMc)12 form an octahedron the cluster having crystalographic C 3v symmetry. Each metal atom is square‐antiprismatically coordinated by eight oxygen atoms. In Zr 4 O 2(OMc)12, the zirconium atoms have a distorted butterfly arrangement; their coordination geometry is square‐antiprismatically coordinated by eight oxygen atomes. In Zr 4 O 2)OMc)12, the zirconium atoms have a distorted butterfly arrangement; their coordination geometry is square‐antiprismatic or capped octahedral.
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Cited by
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Pierre, A. C., & Pajonk, G. M. (2002) · Chemical Reviews · doi:10.1021/cr0101306 · Cited by 2,239
Valenzano, L., Civalleri, B., Chavan, S., Bordiga, S., Nilsen, M. H., Jakobsen, S., Lillerud, K. P., & Lamberti, C. (2011) · Chemistry of Materials · doi:10.1021/cm1022882 · Cited by 1,919
Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals
Van den Eynden, D., Pokratath, R., & De Roo, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01008 · Cited by 83
Mechanistic insights in Zr-and Hf-based molecular hybrid EUV photoresists
Wu, L., Baljozovic, M., Portale, G., Kazazis, D., Vockenhuber, M., Jung, T., Ekinci, Y., & Castellanos Ortega, S. (2019) · Journal of Micro/Nanopatterning Materials and Metrology · doi:10.1117/1.jmm.18.1.013504 · Cited by 49
Kataoka, S., & Sue, K. (2022) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.202200050 · Cited by 26
Metadata
- Authors
- Kickelbick, G., & Schubert, U.
- Venue
- Chemische Berichte
- Publisher
- Wiley
- Published
- 1997-04
- Volume
- 130
- Issue
- 4
- Pages
- 473-478
- ISSN
- 0009-2940 (ISSN-L)
- OpenAlex
- W2108322631
- Cited by
- 209
- References
- 0
- FWCI
- 4.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Oxozirconium Methacrylate Clusters: Zr6(OH)4O4(OMc)12 and Zr4O2(OMc)12 (OMc = Methacrylate). https://app.cochat.ai/papers/10.1002/cber.19971300406
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- Kickelbick, G., & Schubert, U. (1997). Oxozirconium Methacrylate Clusters: Zr6(OH)4O4(OMc)12 and Zr4O2(OMc)12 (OMc = Methacrylate). Chemische Berichte. https://doi.org/10.1002/cber.19971300406
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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