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Chemoselective Hydrogenolysis of Tetrahydropyran‐2‐methanol to 1,6‐Hexanediol over Rhenium‐Modified Carbon‐Supported Rhodium Catalysts
Abstract
Modification of Rh/C with Re species enabled chemoselective hydrogenolysis of tetrahydropyran‐2‐methanol to 1,6‐hexanediol. In particular, the Rh–ReOx/C (Re/Rh ratio=0.25) catalyst gave a high yield of 1,6‐hexanediol (84 %) and showed a very low activity for overhydrogenolysis to 1‐hexanol. Using the same catalyst in the hydrogenolysis of tetrahydrofurfuryl alcohol also gave a high yield of 1,5‐pentanediol (94 %). Characterization results indicate the formation of ReOx clusters attached on the surface of Rh metal particles. This can cause the synergy between ReOx and Rh, and the tetrahydropyran‐2‐methanol hydrogenolysis proceeds on the interface between Rh metal surface and attached ReOx species.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Biorefineries: Current status, challenges, and future direction
Fernando, S., Adhikari, S., Chandrapal, C., & Murali, N. (2006) · Energy & Fuels · doi:10.1021/ef060097w · Cited by 709
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Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Buntara, T., Noel, S., Phua, P. H., Melián‐Cabrera, I., de Vries, J. G., & Heeres, H. J. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102156 · Cited by 477
Nakagawa, Y., Nakazawa, H., Watanabe, H., & Tomishige, K. (2012) · ChemCatChem · doi:10.1002/cctc.201200218 · Cited by 284
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Metadata
- Authors
- Chen, K., Koso, S., Kubota, T., Nakagawa, Y., & Tomishige, K.
- Venue
- ChemCatChem
- Publisher
- Wiley
- Published
- 2010-04-30
- Volume
- 2
- Issue
- 5
- Pages
- 547-555
- ISSN
- 1867-3880 (ISSN-L)
- 1867-3899
- OpenAlex
- W2142875984
- Cited by
- 178
- References
- 2
- FWCI
- 7.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, K., Koso, S., Kubota, T., Nakagawa, Y., & Tomishige, K. (2010). Chemoselective Hydrogenolysis of Tetrahydropyran‐2‐methanol to 1,6‐Hexanediol over Rhenium‐Modified Carbon‐Supported Rhodium Catalysts. ChemCatChem. https://doi.org/10.1002/cctc.201000018
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