The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
New Strategies for the Generation of Large Heteropolymetalate Clusters: The β‐B‐SbW9 Fragment as a Multifunctional Unit
Abstract
Proceeding from the α‐B‐SbW 9 O 33 fragment 1, various novel large heteropolyanions ([Na 2 Sb 8 W 36 O 132(H 2 O)4]22– (2), [Sb 2 W 22 O 74(OH)2]12− (3) and [Sb 2 W 20 M 2 O 70(H 2 O)6](14−2 n)− (4); Mn+ = Fe 3+, Co 2+, Mn 2+, Ni 2+) have been obtained in crystalline form by systematic synthesis. Their unexpected structures have been studied by X‐ray diffraction: 2, 3 and 4 contain β‐SbW 9 units connected to each other by Sb 3+ ions, WO 2/WO 2 OH groups, and WO 2/Mn+ (H 2 O)3 groups, respectively. Structural details and especially the systematic synthesis strategy for the formation of these interesting polytungstates are discussed in order to explain the unusual behaviour of 1 in aqueous solution under different reaction conditions.
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Cites
Heteropoly and Isopoly Oxometalates
Pope, M. T. (1983) · Inorganic chemistry concepts · doi:10.1007/978-3-662-12004-0 · Cited by 4,749
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
Pope, M. T., & Müller, A. (1991) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199100341 · Cited by 3,645
Metal Oxide Chemistry in Solution: The Early Transition Metal Polyoxoanions
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A 'smart' catalyst that self-assembles under turnover conditions
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Zhao, J.-W., Li, Y.-Z., Chen, L.-J., & Yang, G.-Y. (2016) · Chemical Communications · doi:10.1039/c5cc10447e · Cited by 284
Cai, Q., Gao, R., Wang, Y., Xing, J., Zhang, Q., Zhu, M., Qin, X., Liao, M., & Huang, Y. (2025) · Polyoxometalates · doi:10.26599/pom.2024.9140083 · Cited by 22
Rostovtsev, V. V., Green, L. G., Fokin, V. V., & Sharpless, K. B. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4
Metadata
- Authors
- Bösing, M., Loose, I., Pohlmann, H., & Krebs, B.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 1997-08
- Volume
- 3
- Issue
- 8
- Pages
- 1232-1237
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2059200325
- Cited by
- 262
- References
- 7
- FWCI
- 4.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bösing, M., Loose, I., Pohlmann, H., & Krebs, B. (1997). New Strategies for the Generation of Large Heteropolymetalate Clusters: The β‐B‐SbW9 Fragment as a Multifunctional Unit. Chemistry – A European Journal. https://doi.org/10.1002/chem.19970030810
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