SSZ‐53 and SSZ‐59: Two Novel Extra‐Large Pore Zeolites
Abstract
The syntheses, structure solutions, and physicochemical and catalytic characterizations of the novel zeolites SSZ‐53 and SSZ‐59 are described. SSZ‐53 and SSZ‐59 were synthesized under hydrothermal conditions with the [1‐(4‐fluorophenyl)cyclopentylmethyl]trimethyl ammonium cation and 1‐[1‐(4‐chlorophenyl)cyclopentylmethyl]‐1‐methyl azocanium cation, respectively, as structure‐directing agents. The framework topology of SSZ‐53 was solved with the FOCUS method, and the structure of SSZ‐59 was determined by model building. Rietveld refinement of synchrotron X‐ray powder diffraction data confirms each proposed model. SSZ‐53 and SSZ‐59 each possess a one‐dimensional channel system delimited by 14‐membered rings. Results from transmission electron microscopy, electron diffraction, catalytic experiments (spaciousness index and constraint index tests), and argon and hydrocarbon adsorption experiments are consistent with the proposed structures.
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B-silicate zeolites are often produced with different structures than Al-substituted zeolites.
“Importantly, very often, B-silicate zeolites are produced with different structures than Al-substituted zeolites.62−65”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [63]
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Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126 · see citing works
Extra-Large-Pore Zeolites with Two-Dimensional Channels Formed by 14 and 12 Rings
Paillaud, J.-L., Harbuzaru, B., Patarin, J., & Bats, N. (2004) · Science · doi:10.1126/science.1098242 · Cited by 355 · see citing works
Translating new materials discoveries in zeolite research to commercial manufacture
Zones, S. I. (2011) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2011.03.039 · Cited by 227 · see citing works
Self-citation
- Authors
- Burton, A., Elomari, S., Chen, C., Medrud, R. C., Chan, I. Y., Bull, L. M., Kibby, C., Harris, T. V., Zones, S. I., & Vittoratos, E. S.
- Corresponding author
- Burton, Allen
- Elomari, Saleh
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2003-11-28
- Volume
- 9
- Issue
- 23
- Pages
- 5737-5748
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2151159767
- Cited by
- 151
- References
- 0
- Citations by year
- 2026: 7 · 2025: 2 · 2024: 5 · 2023: 3 · 2022: 8 · 2021: 2 · 2020: 2 · 2019: 5 · 2018: 4 · 2017: 7 · 2016: 7 · 2015: 1 · 2014: 9 · 2013: 10 · 2012: 6
- FWCI
- 6.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry - A European Journal (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Division of Materials Research
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Keywords
- extra-large pore zeolites, zeolite synthesis, structure-directing agent, framework topology, zeolite catalysis, hydrocarbon adsorption, argon adsorption
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