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Task‐Specific Ionic Liquids Bearing 2‐Hydroxybenzylamine Units: Synthesis and Americium‐Extraction Studies
Abstract
The synthesis of two task‐specific ionic liquids (TSILs) bearing 2‐hydroxybenzylamine entities is described. These compounds are based on an imidazolium substructure onto which one hydrobenzylamine‐complexing moiety is grafted. We have demonstrated that, whether pure or diluted, TSIL is able to extract americium ions. Furthermore, recovery of americium from the IL phase into a receiving phase can be achieved under acidic conditions. A possible mechanism for the metal‐ion partitioning is presented, in which the extraction system is driven by an ion‐exchange mechanism.
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Citations
Cites
pH-Dependent partitioning in room temperature ionic liquids
Visser, A. E., Swatloski, R. P., & Rogers, R. D. (2000) · Green Chemistry · doi:10.1039/a908888a · Cited by 281
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Sun, X., Luo, H., & Dai, S. (2012) · Chemical Reviews · doi:10.1021/cr200193x · Cited by 852
Recent Applications of Ionic Liquids in Separation Technology
Han, D., & Row, K. H. (2010) · Molecules · doi:10.3390/molecules15042405 · Cited by 560
Mori, T., Takao, K., Sasaki, K., Suzuki, T., Arai, T., & Ikeda, Y. (2015) · Separation and Purification Technology · doi:10.1016/j.seppur.2015.01.045 · Cited by 45
Metadata
- Authors
- Ouadi, A., Gadenne, B., Hesemann, P., Moreau, J. J. E., Billard, I., Gaillard, C., Mekki, S., & Moutiers, G.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2006-03-27
- Volume
- 12
- Issue
- 11
- Pages
- 3074-3081
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2115557082
- Cited by
- 167
- References
- 1
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ouadi, A., Gadenne, B., Hesemann, P., Moreau, J. J. E., Billard, I., Gaillard, C., Mekki, S., & Moutiers, G. (2006). Task‐Specific Ionic Liquids Bearing 2‐Hydroxybenzylamine Units: Synthesis and Americium‐Extraction Studies. Chemistry – A European Journal. https://doi.org/10.1002/chem.200500741
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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