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Functional Organogel Based on a Salicylideneaniline Derivative with Enhanced Fluorescence Emission and Photochromism

Xue, Pengchong, Lu, Ran, Chen, Guojun, Zhang, Yuan, Nomoto, Hiroyuki, Takafuji, Makoto, Ihara, Hirotaka·2007·Chemistry – A European Journal

Abstract

A new organogelator based on a salicylideneaniline derivative with cholesterol moieties was synthesized, and it was proposed that it could gelate various organic solvents, such as 1‐butanol, 1‐octanol, butyl acetate, tetrachloromethane, benzene, toluene through combination with a gelation test. From the results of analysis by UV/Vis absorption, circular dichroism (CD), X‐ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) studies and semiempirical (AM1) calculations, we believed that the gelator molecules could self‐assemble into left‐handed helical nanofibers through unimolecular layer packing, which further twisted into the thicker fibers and constructed 3D networks in the gel phase. Interestingly, the organogel exhibited strong fluorescence enhancement relative to a solution of the same concentration because of the formation of J aggregations. Meanwhile, photochromism of the organogel could take place under UV‐light irradiation. Both strong fluorescence emission and photochromism properties were concurrent in one system based on a salicylideneaniline derivative. It was suggested that the self‐assembly of the functional organogelator could lead to unique photophysical properties.

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Metadata

Authors
Xue, P., Lu, R., Chen, G., Zhang, Y., Nomoto, H., Takafuji, M., & Ihara, H.
Venue
Chemistry – A European Journal
Publisher
Wiley
Published
2007-09-25
Volume
13
Issue
29
Pages
8231-8239
ISSN
  • 0947-6539 (ISSN-L)
  • 1521-3765
OpenAlex
W2080720280
Cited by
192
References
2
FWCI
7.39
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Functional Organogel Based on a Salicylideneaniline Derivative with Enhanced Fluorescence Emission and Photochromism. https://app.cochat.ai/papers/10.1002/chem.200700321
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Xue, P., Lu, R., Chen, G., Zhang, Y., Nomoto, H., Takafuji, M., & Ihara, H. (2007). Functional Organogel Based on a Salicylideneaniline Derivative with Enhanced Fluorescence Emission and Photochromism. Chemistry – A European Journal. https://doi.org/10.1002/chem.200700321

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