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Surfactant‐Free Synthesis of Hyperbranched Monoclinic Bismuth Vanadate and its Applications in Photocatalysis, Gas Sensing, and Lithium‐Ion Batteries
Abstract
Hyperbranched monoclinic BiVO 4 (h‐BiVO 4) has been synthesized on a large scale and with good uniformity by a surfactant‐free hydrothermal route. h‐BiVO 4 consists of four trunks with branches distributed on opposite sides. From observation of the intermediates at an early stage of the reaction process, it can be seen that during formation h‐BiVO 4 has different growth rates along the a, b, and c axes. Based on crystal structure analysis and experimental results, h‐BiVO 4 shows preferential growth along the [100] direction, and subsequently, along the [010] and [001] directions. As‐synthesized h‐BiVO 4 exhibits excellent photocatalytic ability in the photodegradation reaction of an aqueous solution of RB under visible light. Electrochemical measurements predict that h‐BiVO 4 possesses high sensitivity to formaldehyde and ethanol gases, favorable discharge capacity, and capacity retention, which indicate potential applications in the fields of sensing devices and lithium‐ion batteries.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
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Advanced Nanoarchitectures for Solar Photocatalytic Applications
Kubacka, A., Fernández-García, M., & Colón, G. (2012) · Chemical Reviews · doi:10.1021/cr100454n · Cited by 2,373
Recent Advances in Nanostructured Vanadium Oxides and Composites for Energy Conversion
Liu, M., Su, B., Tang, Y., Jiang, X., & Yu, A. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700885 · Cited by 293
Shang, M., Wang, W., Zhang, L., Sun, S., Wang, L., & Zhou, L. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9045808 · Cited by 278
Metadata
- Authors
- Zhao, Y., Xie, Y., Zhu, X., Yan, S., & Wang, S.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2008-02
- Volume
- 14
- Issue
- 5
- Pages
- 1601-1606
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2122892071
- Cited by
- 203
- References
- 1
- FWCI
- 7.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, Y., Xie, Y., Zhu, X., Yan, S., & Wang, S. (2008). Surfactant‐Free Synthesis of Hyperbranched Monoclinic Bismuth Vanadate and its Applications in Photocatalysis, Gas Sensing, and Lithium‐Ion Batteries. Chemistry – A European Journal. https://doi.org/10.1002/chem.200701053
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