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Multifunctional Fourfold Interpenetrating Diamondoid Network: Gas Separation and Fabrication of Palladium Nanoparticles
Abstract
A fourfold interpenetrating diamondoid network, [{[Ni(cyclam)]2(mtb)}n]⋅8 n H 2 O⋅4 n DMF (1) (MTB=methanetetrabenzoate, DMF=dimethylformamide), has been assembled from [Ni(cyclam)][ClO 4]2 (cyclam=1,4,8,11‐tetraazacyclotetradecane) and methanetetrabenzoic acid (H 4 MTB) in DMF/H 2 O (7:3, v/v) in the presence of triethylamine (TEA). Despite the high‐fold interpenetration, 1 generates 1D channels that are occupied by water and DMF guest molecules. Solid 1, after removal of guest molecules, exhibits selective gas adsorption behavior for H 2, CO 2, and O 2 rather than N 2 and CH 4, suggesting possible applications in gas separation technologies. In addition, solid 1 can be applied in the fabrication of small Pd (2.0±0.6 nm) nanoparticles without any extra reducing or capping agent because a Ni II macrocyclic species incorporated in 1 reduces Pd II ions to Pd 0 on immersion of 1 in the solution of Pd(NO 3)2⋅2 H 2 O in MeCN at room temperature.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Metal–organic framework composites
Zhu, Q.-L., & Xu, Q. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60472a · Cited by 2,286
Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
Yang, Q., Xu, Q., & Jiang, H.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00724d · Cited by 1,892
Perspective of microporous metal–organic frameworks for CO2capture and separation
Zhang, Z., Yao, Z.-Z., Xiang, S., & Chen, B. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00143e · Cited by 767
Metadata
- Authors
- Cheon, Y. E., & Suh, M. P.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2008-04-18
- Volume
- 14
- Issue
- 13
- Pages
- 3961-3967
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2105674418
- Cited by
- 186
- References
- 0
- FWCI
- 13.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cheon, Y. E., & Suh, M. P. (2008). Multifunctional Fourfold Interpenetrating Diamondoid Network: Gas Separation and Fabrication of Palladium Nanoparticles. Chemistry – A European Journal. https://doi.org/10.1002/chem.200701813
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