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Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride
Open accessAbstract
Herein we report the synthesis of a crystalline graphitic carbon nitride, or g‐C 3 N 4, obtained from the temperature‐induced condensation of dicyandiamide (NH 2 C(NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g‐C 3 N 4 species is based on sheets of hexagonally arranged s‐heptazine (C 6 N 7) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X‐ray diffractometry and high‐resolution transmission electron microscopy.
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Citations
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine
Yan, S. C., Li, Z. S., & Zou, Z. G. (2009) · Langmuir · doi:10.1021/la900923z · Cited by 2,777
Lu, W., Qin, X., Liu, S., Chang, G., Zhang, Y., Luo, Y., Asiri, A. M., Al-Youbi, A. O., & Sun, X. (2012) · Analytical Chemistry · doi:10.1021/ac3007939 · Cited by 1,163
Dong, G., Zhang, Y., Pan, Q., & Qiu, J. (2014) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2014.04.002 · Cited by 1,085
Metadata
- Authors
- Bojdys, M. J., Müller, J., Antonietti, M., & Thomas, A.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2008-09-15
- Volume
- 14
- Issue
- 27
- Pages
- 8177-8182
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2146683198
- Cited by
- 1,230
- References
- 0
- FWCI
- 11.61
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Bojdys, M. J., Müller, J., Antonietti, M., & Thomas, A. (2008). Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride. Chemistry – A European Journal. https://doi.org/10.1002/chem.200800190
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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