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TEMPO Supported on Magnetic C/Co‐Nanoparticles: A Highly Active and Recyclable Organocatalyst
Abstract
TEMPO was grafted on graphene‐coated nanobeads with a magnetic cobalt core by using a general applicable “click”‐chemistry protocol. The new heterogeneous CoNP–TEMPO emerged as a highly active catalyst for the chemoselective oxidation of primary and secondary alcohols using bleach as terminal oxidant. The outstanding stability of the C/Co nanoparticles enables the nanopowder to tolerate several TEMPO‐mediated iterative oxidation reactions without any significant loss in catalyst activity. Furthermore, the excellent magnetic properties enable the rapid separation and quantitative recycling of CoNP–TEMPO out of the reaction mixture by simple magnetic decantation. The recovered nanoparticles can be subsequently reused without any further purification.
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Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
Cited by
Metal chelating systems synthesized using the copper(i) catalyzed azide-alkynecycloaddition
Struthers, H., Mindt, T. L., & Schibli, R. (2010) · Dalton Trans. · doi:10.1039/b912608b · Cited by 386
Kainz, Q. M., & Reiser, O. (2014) · Accounts of Chemical Research · doi:10.1021/ar400236y · Cited by 304
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Metadata
- Authors
- Schätz, A., Grass, R. N., Stark, W. J., & Reiser, O.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2008-09-15
- Volume
- 14
- Issue
- 27
- Pages
- 8262-8266
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2160495495
- Cited by
- 172
- References
- 1
- FWCI
- 8.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schätz, A., Grass, R. N., Stark, W. J., & Reiser, O. (2008). TEMPO Supported on Magnetic C/Co‐Nanoparticles: A Highly Active and Recyclable Organocatalyst. Chemistry – A European Journal. https://doi.org/10.1002/chem.200801001
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