The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Ruthenium‐Catalyzed Dimethylamineborane Dehydrogenation: Stepwise Metal‐Centered Dehydrocyclization
Abstract
Amine–borane dehydrogenation: Ruthenium PNP amido pincer complex I catalyzes the dehydrocoupling of dimethylamineborane to cyclic dimer (Me2NBH2)2. The results are in agreement with a mechanism including initial alternative dehydrogenation to aminoborane Me2NBH2 versus metal-centered BN coupling via diborazane Me2HNH2BMe2NBH3. Formation of borametallacycle II, which features a rare four-membered Ru–N–B–H ring, results in considerable slowdown of the catalytic activity.
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Citations
Cites
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Cited by
Bond Activation and Catalysis by Ruthenium Pincer Complexes
Gunanathan, C., & Milstein, D. (2014) · Chemical Reviews · doi:10.1021/cr5002782 · Cited by 958
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
Alig, L., Fritz, M., & Schneider, S. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00555 · Cited by 887
Self-citationAmmonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides
Rossin, A., & Peruzzini, M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00043 · Cited by 421
Staubitz, A., Sloan, M. E., Robertson, A. P. M., Friedrich, A., Schneider, S., Gates, P. J., Schmedt auf der Günne, J., & Manners, I. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104607y · Cited by 302
Self-citationSchneider, S., Meiners, J., & Askevold, B. (2012) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201100880 · Cited by 276
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Metadata
- Authors
- Friedrich, A., Drees, M., & Schneider, S.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2009-10-06
- Volume
- 15
- Issue
- 40
- Pages
- 10339-10342
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2024489740
- Cited by
- 203
- References
- 1
- FWCI
- 10.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Friedrich, A., Drees, M., & Schneider, S. (2009). Ruthenium‐Catalyzed Dimethylamineborane Dehydrogenation: Stepwise Metal‐Centered Dehydrocyclization. Chemistry – A European Journal. https://doi.org/10.1002/chem.200901372
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
