The DOI matches its Crossref record; 84 of the 84 references it cites were found in a registry or an index.
Synthesis of a Metal–Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study
Abstract
A metal–organic framework material named MIL‐53(Fe), iron terephthalate, has been synthesized sovothermally at a relatively low temperature by not only conventional electric (CE) heating, but also by irradiation under ultrasound (US) and microwave (MW) conditions to gain an understanding of the accelerated syntheses induced by US and MW. The kinetics for nucleation and crystal growth were analyzed by measuring the crystallinity of MIL‐53(Fe) under various conditions. The nucleation and crystal growth rates were estimated from crystallization curves of the change in crystallinity with reaction time. The activation energies and pre‐exponential factors were calculated from Arrhenius plots. It was confirmed that the rate of crystallization (both nucleation and crystal growth) decreases in the order US>MW≫CE, and that the accelerated syntheses under US and MW conditions are due to increased pre‐exponential factors rather than decreased activation energies. It is suggested that physical effects such as hot spots are more important than chemical effects in the accelerated syntheses induced by US and MW irradiation. The syntheses were also conducted in two steps to understand quantitatively the acceleration induced by MW and it was found that the acceleration in crystal growth is more important than the acceleration in nucleation, even though both processes are accelerated by MW irradiation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
Reticular synthesis and the design of new materials
Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003) · Nature · doi:10.1038/nature01650 · Cited by 9,101
Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., & Yaghi, O. M. (2002) · Science · doi:10.1126/science.1067208 · Cited by 8,132
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
Luminescent metal–organic frameworks
Allendorf, M. D., Bauer, C. A., Bhakta, R. K., & Houk, R. J. T. (2009) · Chemical Society Reviews · doi:10.1039/b802352m · Cited by 4,960
Hydrogen storage in metal–organic frameworks
Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532
A homochiral metal–organic porous material for enantioselective separation and catalysis
Seo, J. S., Whang, D., Lee, H., Jun, S. I., Oh, J., Jeon, Y. J., & Kim, K. (2000) · Nature · doi:10.1038/35010088 · Cited by 3,924
Enantioselective catalysis with homochiral metal–organic frameworks
Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Cited by
Modified metal-organic frameworks as photocatalysts
Qiu, J., Zhang, X., Feng, Y., Zhang, X., Wang, H., & Yao, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.03.039 · Cited by 499
Liu, X., Zhou, Y., Zhang, J., Tang, L., Luo, L., & Zeng, G. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02563 · Cited by 312
Aerogels and metal–organic frameworks for environmental remediation and energy production
Kumar, A., Rana, A., Sharma, G., Sharma, S., Naushad, M., Mola, G. T., Dhiman, P., & Stadler, F. J. (2018) · Environmental Chemistry Letters · doi:10.1007/s10311-018-0723-x · Cited by 75
Metadata
- Authors
- Haque, E., Khan, N. A., Park, J. H., & Jhung, S. H.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2010-01-14
- Volume
- 16
- Issue
- 3
- Pages
- 1046-1052
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2144504794
- Cited by
- 369
- References
- 84
- FWCI
- 9.19
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Synthesis of a Metal–Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study. https://app.cochat.ai/papers/10.1002/chem.200902382
- The paper
- Haque, E., Khan, N. A., Park, J. H., & Jhung, S. H. (2010). Synthesis of a Metal–Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study. Chemistry – A European Journal. https://doi.org/10.1002/chem.200902382
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
