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Graphene‐Encapsulated Fe3O4 Nanoparticles with 3D Laminated Structure as Superior Anode in Lithium Ion Batteries
Abstract
Fe 3 O 4–graphene composites with three‐dimensional laminated structures have been synthesised by a simple in situ hydrothermal method. From field‐emission and transmission electron microscopy results, the Fe 3 O 4 nanoparticles, around 3–15 nm in size, are highly encapsulated in a graphene nanosheet matrix. The reversible Li‐cycling properties of Fe 3 O 4–graphene have been evaluated by galvanostatic discharge–charge cycling, cyclic voltammetry and impedance spectroscopy. Results show that the Fe 3 O 4–graphene nanocomposite with a graphene content of 38.0 wt % exhibits a stable capacity of about 650 mAh g−1 with no noticeable fading for up to 100 cycles in the voltage range of 0.0–3.0 V. The superior performance of Fe 3 O 4–graphene is clearly established by comparison of the results with those from bare Fe 3 O 4. The graphene nanosheets in the composite materials could act not only as lithium storage active materials, but also as an electronically conductive matrix to improve the electrochemical performance of Fe 3 O 4.
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Cited by
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Chen, D., Ji, G., Ma, Y., Lee, J. Y., & Lu, J. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am200592r · Cited by 298
Min, J., Wen, X., Tang, T., Chen, X., Huo, K., Gong, J., Azadmanjiri, J., He, C., & Mijowska, E. (2020) · Chemical Communications · doi:10.1039/d0cc03236k · Cited by 78
Nitrogen-doped porous carbon/graphene aerogel with much enhanced capacitive behaviors
Wang, C., Huang, Y., Pan, H., Jiang, J., Yang, X., Xu, Z., Tian, H., Han, S., & Wu, D. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.08.077 · Cited by 33
Metadata
- Authors
- Wang, J., Zhong, C., Wexler, D., Idris, N. H., Wang, Z., Chen, L., & Liu, H.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2010-11-05
- Volume
- 17
- Issue
- 2
- Pages
- 661-667
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2130240910
- Cited by
- 405
- References
- 0
- FWCI
- 34.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, J., Zhong, C., Wexler, D., Idris, N. H., Wang, Z., Chen, L., & Liu, H. (2011). Graphene‐Encapsulated Fe3O4 Nanoparticles with 3D Laminated Structure as Superior Anode in Lithium Ion Batteries. Chemistry – A European Journal. https://doi.org/10.1002/chem.201001348
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