The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Chemical and Thermal Stability of Isotypic Metal–Organic Frameworks: Effect of Metal Ions
Abstract
Chemical and thermal stabilities of isotypic metal–organic frameworks (MOFs) like Al‐BDC (Al‐benzenedicarboxylate called MIL‐53‐Al), Cr‐BDC (MIL‐53‐Cr) and V‐BDC (MIL‐47‐V), after purification to remove uncoordinated organic linkers, have been compared to understand the effect of the central metal ions on the stabilities of the porous MOF‐type materials. Chemical stability to acids, bases, and water decreases in the order of Cr‐BDC>Al‐BDC>V‐BDC, suggesting stability increases with increasing inertness of the central metal ions. However, thermal stability decreases in the order of Al‐BDC>Cr‐BDC> V‐BDC, and this tendency may be explained by the strength of the metal–oxygen bond in common oxides like Al 2 O 3, Cr 2 O 3, and V 2 O 5. In order to evaluate precisely the stability of a MOF, it is necessary to remove uncoordinated organic linkers that are located in the pores of the MOF, because a filled MOF may be more stable than the same MOF after purification.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Water adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
Metal–Organic Frameworks for Water Harvesting from Air
Kalmutzki, M. J., Diercks, C. S., & Yaghi, O. M. (2018) · Advanced Materials · doi:10.1002/adma.201704304 · Cited by 772
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Metal–organic frameworks (MOFs) for the removal of emerging contaminants from aquatic environments
Dhaka, S., Kumar, R., Deep, A., Kurade, M. B., Ji, S.-W., & Jeon, B.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.10.003 · Cited by 615
Metadata
- Authors
- Kang, I. J., Khan, N. A., Haque, E., & Jhung, S. H.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2011-05-05
- Volume
- 17
- Issue
- 23
- Pages
- 6437-6442
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2047916257
- Cited by
- 334
- References
- 2
- FWCI
- 10.03
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kang, I. J., Khan, N. A., Haque, E., & Jhung, S. H. (2011). Chemical and Thermal Stability of Isotypic Metal–Organic Frameworks: Effect of Metal Ions. Chemistry – A European Journal. https://doi.org/10.1002/chem.201100316
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