The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Understanding the Anomalous Alkane Selectivity of ZIF‐7 in the Separation of Light Alkane/Alkene Mixtures
Abstract
C2 and C3 alkanes are selectively adsorbed from mixtures over the corresponding alkenes on the zeolite imidazolate framework ZIF‐7 through a gate‐opening mechanism. As a result, the direct production of the pure alkene upon adsorption and the pure alkane upon desorption in packed columns is possible. Herein, a detailed investigation of the step‐wise adsorption and separation of alkanes and alkenes is presented, together with a rigorous performance assessment. A molecular picture of the gate‐opening mechanism underlying the unprecedented selectivity towards alkane adsorption is proposed based on DFT calculations and a thermodynamic analysis of the adsorption–desorption isotherms.
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Cites
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O’Keeffe, M., & Yaghi, O. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602439103 · Cited by 7,563
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A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon Hydration
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Cited by
Metal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Metal Organic Framework Catalysis: Quo vadis?
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Self-citationRezakazemi, M., Ebadi Amooghin, A., Montazer-Rahmati, M. M., Ismail, A. F., & Matsuura, T. (2014) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.01.003 · Cited by 853
ZIF-8: A comparison of synthesis methods
Lee, Y.-R., Jang, M.-S., Cho, H.-Y., Kwon, H.-J., Kim, S., & Ahn, W.-S. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.02.094 · Cited by 849
Yang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
Metadata
- Authors
- van den Bergh, J., Gücüyener, C., Pidko, E. A., Hensen, E. J. M., Gascon, J., & Kapteijn, F.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2011-07-13
- Volume
- 17
- Issue
- 32
- Pages
- 8832-8840
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W1970153368
- Cited by
- 292
- References
- 45
- FWCI
- 15.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- van den Bergh, J., Gücüyener, C., Pidko, E. A., Hensen, E. J. M., Gascon, J., & Kapteijn, F. (2011). Understanding the Anomalous Alkane Selectivity of ZIF‐7 in the Separation of Light Alkane/Alkene Mixtures. Chemistry – A European Journal. https://doi.org/10.1002/chem.201100958
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