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Subtle Ligand Effects in Oxidative Photocatalysis with Iridium Complexes: Application to Photopolymerization
Abstract
Iridium(III) complexes were designed and evaluated as efficient photoinitiators of polymerization reactions in combination with iodonium salts and silanes. Mechanistically, these reactions were shown to proceed through oxidative photoredox catalysis, generating aryl and silyl radicals under very soft irradiation conditions (blue LED, xenon lamp, and even sunlight). These radicals can initiate the free radical polymerization of acrylates or can be oxidized during the catalytic cycle to promote the ring‐opening polymerization of epoxy monomers. Remarkably, both the (photo)chemical reactivity and the practical efficiency are dramatically affected by the ligands. In addition, the central role played by the oxidation ability of the excited state of the photocatalyst is discussed.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Triplet photosensitizers: from molecular design to applications
Zhao, J., Wu, W., Sun, J., & Guo, S. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35531d · Cited by 1,579
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Xu, J., Jung, K., Atme, A., Shanmugam, S., & Boyer, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501745g · Cited by 990
Photoinduced Electron Transfer Reactions for Macromolecular Syntheses
Dadashi-Silab, S., Doran, S., & Yagci, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00586 · Cited by 846
Metadata
- Authors
- Lalevée, J., Peter, M., Dumur, F., Gigmes, D., Blanchard, N., Tehfe, M., Morlet‐Savary, F., & Fouassier, J. P.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2011-11-28
- Volume
- 17
- Issue
- 52
- Pages
- 15027-15031
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2150953134
- Cited by
- 174
- References
- 0
- FWCI
- 9.28
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lalevée, J., Peter, M., Dumur, F., Gigmes, D., Blanchard, N., Tehfe, M., Morlet‐Savary, F., & Fouassier, J. P. (2011). Subtle Ligand Effects in Oxidative Photocatalysis with Iridium Complexes: Application to Photopolymerization. Chemistry – A European Journal. https://doi.org/10.1002/chem.201101445
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