The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Iron Metal–Organic Frameworks MIL‐88B and NH2‐MIL‐88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide
Abstract
Crystals of MIL‐88B‐Fe and NH 2‐MIL‐88B‐Fe were prepared by a new rapid microwave‐assisted solvothermal method. High‐purity, spindle‐shaped crystals of MIL‐88B‐Fe with a length of about 2 μm and a diameter of 1 μm and needle‐shaped crystals of NH 2‐MIL‐88B‐Fe with a length of about 1.5 μm and a diameter of 300 nm were produced with uniform size and excellent crystallinity. The possibility to reduce the as‐prepared frameworks and the chemical capture of carbon monoxide in these materials was studied by in situ ultrahigh vacuum Fourier‐transform infrared (UHV‐FTIR) spectroscopy and Mössbauer spectroscopy. CO binding occurs to unsaturated coordination sites (CUS). The release of CO from the as‐prepared materials was studied by a myoglobin assay in physiological buffer. The release of CO from crystals of MIL‐88B‐Fe with t1/2=38 min and from crystals of NH 2‐MIL‐88B‐Fe with t1/2=76 min were found to be controlled by the degradation of the MIL materials under physiological conditions. These MIL‐88B‐Fe and NH 2‐MIL‐88B‐Fe materials show good biocompatibility and have the potential to be used in pharmacological and therapeutic applications as carriers and delivery vehicles for the gasotransmitter carbon monoxide.
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Citations
Cites
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Cited by
Liu, X., Zhou, Y., Zhang, J., Tang, L., Luo, L., & Zeng, G. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02563 · Cited by 312
Biocompatibility and biodegradability of metal organic frameworks for biomedical applications
Singh, N., Qutub, S., & Khashab, N. M. (2021) · Journal of Materials Chemistry B · doi:10.1039/d1tb01044a · Cited by 303
Metadata
- Authors
- Ma, M., Noei, H., Mienert, B., Niesel, J., Bill, E., Muhler, M., Fischer, R. A., Wang, Y., Schatzschneider, U., & Metzler‐Nolte, N.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2013-03-27
- Volume
- 19
- Issue
- 21
- Pages
- 6785-6790
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2112162864
- Cited by
- 171
- References
- 1
- FWCI
- 5.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Iron Metal–Organic Frameworks MIL‐88B and NH2‐MIL‐88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide. https://app.cochat.ai/papers/10.1002/chem.201201743
- The paper
- Ma, M., Noei, H., Mienert, B., Niesel, J., Bill, E., Muhler, M., Fischer, R. A., Wang, Y., Schatzschneider, U., & Metzler‐Nolte, N. (2013). Iron Metal–Organic Frameworks MIL‐88B and NH2‐MIL‐88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide. Chemistry – A European Journal. https://doi.org/10.1002/chem.201201743
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