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Two‐Dimensional Tetrathiafulvalene Covalent Organic Frameworks: Towards Latticed Conductive Organic Salts
Abstract
The construction of a new class of covalent TTF lattice by integrating TTF units into two‐dimensional covalent organic frameworks (2D COFs) is reported. We explored a general strategy based on the C 2+C 2 topological diagram and applied to the synthesis of microporous and mesoporous TTF COFs. Structural resolutions revealed that both COFs consist of layered lattices with periodic TTF columns and tetragonal open nanochannels. The TTF columns offer predesigned pathways for high‐rate hole transport, predominate the HOMO and LUMO levels of the COFs, and are redox active to form organic salts that exhibit enhanced electric conductivity by several orders of magnitude. On the other hand, the linkers between the TTF units play a vital role in determining the carrier mobility and conductivity through the perturbation of 2D sheet conformation and interlayer distance. These results open a way towards designing a new type of TTF materials with stable and predesignable lattice structures for functional exploration.
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Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Self-citationInterface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Self-citationBeuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Metadata
- Authors
- Jin, S., Sakurai, T., Kowalczyk, T., Dalapati, S., Xu, F., Wei, H., Chen, X., Gao, J., Seki, S., Irle, S., & Jiang, D.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2014-04-29
- Volume
- 20
- Issue
- 45
- Pages
- 14608-14613
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2123804687
- Cited by
- 172
- References
- 0
- FWCI
- 5.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Jin, S., Sakurai, T., Kowalczyk, T., Dalapati, S., Xu, F., Wei, H., Chen, X., Gao, J., Seki, S., Irle, S., & Jiang, D. (2014). Two‐Dimensional Tetrathiafulvalene Covalent Organic Frameworks: Towards Latticed Conductive Organic Salts. Chemistry – A European Journal. https://doi.org/10.1002/chem.201402844
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