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Construction of a 2D Graphene‐Like MoS2/C3N4 Heterojunction with Enhanced Visible‐Light Photocatalytic Activity and Photoelectrochemical Activity
Abstract
A novel graphene‐like MoS 2/C 3 N 4 (GL‐MoS 2/C 3 N 4) composite photocatalyst has been synthesized by a facile ethylene glycol (EG)‐assisted solvothermal method. The structure and morphology of this GL‐MoS 2/C 3 N 4 photocatalyst have been investigated by a wide range of characterization methods. The results showed that GL‐MoS 2 was uniformly distributed on the surface of GL‐C 3 N 4 forming a heterostructure. The obtained composite exhibited strong absorbing ability in the ultraviolet (UV) and visible regions. When irradiated with visible light, the composite photocatalyst showed high activity superior to those of the respective individual components GL‐MoS 2 and GL‐C 3 N 4 in the degradation of methyl orange. The enhanced photocatalytic activity of the composite may be attributed to the efficient separation of electron–hole pairs as a result of the matching band potentials between GL‐MoS 2 and GL‐C 3 N 4. Furthermore, a photocatalytic mechanism for the composite material has been proposed, and the photocatalytic reaction kinetics has been measured. Moreover, GL‐MoS 2/C 3 N 4 could serve as a novel sensor for trace amounts of Cu 2+ since it exhibited good selectivity for Cu 2+ detection in water.
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Cites
Graphene-based semiconductor photocatalysts
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15172j · Cited by 2,730
Progress, challenge and perspective of heterogeneous photocatalysts
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Removal of dyes from aqueous solution using fly ash and red mud
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Ge, L., Han, C., Xiao, X., & Guo, L. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.04.006 · Cited by 401
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Xia, P., Zhu, B., Cheng, B., Yu, J., & Xu, J. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b03289 · Cited by 630
Recent development on MoS2-based photocatalysis: A review
Li, Z., Meng, X., & Zhang, Z. (2018) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2017.12.002 · Cited by 573
Ren, Y., Zeng, D., & Ong, W.-J. (2019) · Chinese Journal of Catalysis · doi:10.1016/s1872-2067(19)63293-6 · Cited by 528
Li, C., Cao, Q., Wang, F., Xiao, Y., Li, Y., Delaunay, J.-J., & Zhu, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00067k · Cited by 494
Metadata
- Authors
- Yan, J., Chen, Z., Ji, H., Liu, Z., Wang, X., Xu, Y., She, X., Huang, L., Xu, L., Xu, H., & Li, H.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2016-02-02
- Volume
- 22
- Issue
- 14
- Pages
- 4764-4773
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2275630711
- Cited by
- 166
- References
- 6
- FWCI
- 9.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yan, J., Chen, Z., Ji, H., Liu, Z., Wang, X., Xu, Y., She, X., Huang, L., Xu, L., Xu, H., & Li, H. (2016). Construction of a 2D Graphene‐Like MoS2/C3N4 Heterojunction with Enhanced Visible‐Light Photocatalytic Activity and Photoelectrochemical Activity. Chemistry – A European Journal. https://doi.org/10.1002/chem.201503660
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