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Caesium for Perovskite Solar Cells: An Overview
Open accessAbstract
Perovskite solar cells have the potential to revolutionize the world of photovoltaics, and their efficiency close to 23 % on a lab‐scale recently certified this novel technology as the one with the most rapidly raising performance per year in the whole story of solar cells. With the aim of improving stability, reproducibility and spectral properties of the devices, in the last three years the scientific community strongly focused on Cs‐doping for hybrid (typically, organolead) perovskites. In parallel, to further contrast hygroscopicity and reach thermal stability, research has also been carried out to achieve the development of all‐inorganic perovskites based on caesium, the performances of which are rapidly increasing. The potential of caesium is further strengthened when it is used as a modifying agent of charge‐carrier layers in solar cells, but also for the preparation of perovskites with peculiar optoelectronic properties for unconventional applications (e.g., in LEDs, photodetectors, sensors, etc.). This Review offers a 360‐degree overview on how caesium can strongly tune the properties and performance of perovskites and relative perovskite‐based devices.
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Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
Akkerman, Q. A., Gandini, M., Di Stasio, F., Rastogi, P., Palazon, F., Bertoni, G., Ball, J. M., Prato, M., Petrozza, A., & Manna, L. (2016) · Nature Energy · doi:10.1038/nenergy.2016.194 · Cited by 721
Cited by
Stable perovskite solar cells with efficiency exceeding 24.8% and 0.3-V voltage loss
Jeong, M., Choi, I. W., Go, E. M., Cho, Y., Kim, M., Lee, B., Jeong, S., Jo, Y., Choi, H. W., Lee, J., et al. (2020) · Science · doi:10.1126/science.abb7167 · Cited by 1,517
Carbon-based materials for stable, cheaper and large-scale processable perovskite solar cells
Fagiolari, L., & Bella, F. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02115a · Cited by 355
Self-citationA Review of Inorganic Hole Transport Materials for Perovskite Solar Cells
Kung, P., Li, M., Lin, P., Chiang, Y., Chan, C., Guo, T., & Chen, P. (2018) · Advanced Materials Interfaces · doi:10.1002/admi.201800882 · Cited by 293
Low-temperature carbon-based electrodes in perovskite solar cells
Bogachuk, D., Zouhair, S., Wojciechowski, K., Yang, B., Babu, V., Wagner, L., Xu, B., Lim, J., Mastroianni, S., Pettersson, H., et al. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02175j · Cited by 268
Islam, M. S., Islam, M. T., Sarker, S., Jame, H. A., Nishat, S. S., Jani, M. R., Rauf, A., Ahsan, S., Shorowordi, K. M., Efstathiadis, H., et al. (2022) · ACS Omega · doi:10.1021/acsomega.2c01076 · Cited by 76
Metadata
- Authors
- Bella, F., Renzi, P., Cavallo, C., & Gerbaldi, C.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2018-06-27
- Volume
- 24
- Issue
- 47
- Pages
- 12183-12205
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2804286460
- Cited by
- 176
- References
- 2
- FWCI
- 9.69
- Type
- journal article
- Language
- en
- Open access
- green
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