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Molecular Sieve Separations
Abstract
The pore structures of adsorbents such as zeolites and metal‐organic frameworks comprise regular arrays of uniform channels of molecular dimensions, thus offering the possibility of size selective (molecular sieve) separations. Molecular sieve separations have traditionally been carried out in a cyclic batch adsorption/desorption process but, in principle, a steady state membrane process would be an attractive alternative. Considerable success has been achieved at the laboratory scale for several different molecular sieve separations but the difficulty of fabricating, on a large scale, a sufficiently coherent and robust zeolite membrane has largely prevented the commercial application of such processes. Selected examples of kinetic separations are presented in order to illustrate some of the features of such systems.
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“Closely related to this feature, their narrow pore size distribution, i.e., very regular pore sizes, makes them useful for applications, in which size or shape selectivity is involved.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [174]
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Metadata
- Authors
- Ruthven, D. M.
- Affiliations
- University of Maine (US)
- Corresponding author
- Ruthven, Douglas M.
- ORCID
- Ruthven, Douglas M.
- Venue
- Chemie Ingenieur Technik
- Publisher
- Wiley
- Published
- 2011-01
- Volume
- 83
- Issue
- 1-2
- Pages
- 44-52
- ISSN
- 0009-286X (ISSN-L)
- 1522-2640
- OpenAlex
- W2083811320
- Cited by
- 60
- References
- 30
- Citations by year
- 2026: 6 · 2025: 7 · 2024: 5 · 2023: 8 · 2022: 1 · 2021: 5 · 2020: 1 · 2019: 2 · 2017: 5 · 2016: 1 · 2015: 1 · 2014: 4 · 2013: 5 · 2012: 8
- FWCI
- 10.20
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemie Ingenieur Technik (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane Separation and Gas Transport
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Keywords
- zeolite membranes, metal-organic frameworks, size-selective adsorption, kinetic separation, membrane separation, adsorption-desorption cycles, pore structure, industrial scale-up
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