The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Photoinduced FeCl3‐Catalyzed Alkyl Aromatics Oxidation toward Degradation of Polystyrene at Room Temperature†
Abstract
Main observation and conclusion: While polystyrene is widely used in daily life as a synthetic plastic, the subsequently selective degradation is still very challenging and highly required. Herein, we disclose a highly practical and selective reaction for the catalytically efficient oxidation of alkyl aromatics (including 1°, 2°, and 3° alkyl aromatics) to carboxylic acids. While dioxygen was used as the sole terminal oxidant, this protocol was catalyzed by the inexpensive and readily available ferric compound (FeCl 3) with irradiation of visible light (blue LEDs) under only 1 atmosphere of O 2 at room temperature. This system could further facilitate the selective degradation of polystyrene to benzoic acid, providing an important and practical tool to generate high‐value chemical from abundant polystyrene wastes.
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Cites
Production, use, and fate of all plastics ever made
Geyer, R., Jambeck, J. R., & Law, K. L. (2017) · Science Advances · doi:10.1126/sciadv.1700782 · Cited by 18,606
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Physical Mechanisms of Generation and Deactivation of Singlet Oxygen
Schweitzer, C., & Schmidt, R. (2003) · Chemical Reviews · doi:10.1021/cr010371d · Cited by 2,123
Kim, H. R., Lee, H. M., Yu, H. C., Jeon, E., Lee, S., Li, J., & Kim, D.-H. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c01495 · Cited by 334
Sunlight converts polystyrene to carbon dioxide and dissolved organic carbon
Ward, C. P., Armstrong, C. J., Walsh, A. N., Jackson, J. H., & Reddy, C. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00532 · Cited by 253
Cited by
Huang, Z., Shanmugam, M., Liu, Z., Brookfield, A., Bennett, E. L., Guan, R., Vega Herrera, D. E., Lopez-Sanchez, J. A., Slater, A. G., McInnes, E. J. L., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01410 · Cited by 365
Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation
Oh, S., & Stache, E. E. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01411 · Cited by 361
Interactive impacts of photoaged micro(nano)plastics and co-occurring chemicals in the environment
Junaid, M., Hamid, N., Liu, S., Abbas, Z., Imran, M., Haider, M. R., Wang, B., Chen, G., Khan, H. K., Yue, Q., et al. (2024) · Science of The Total Environment · doi:10.1016/j.scitotenv.2024.172213 · Cited by 37
Metadata
- Authors
- Zhang, G., Zhang, Z., & Zeng, R.
- Venue
- Chinese Journal of Chemistry
- Publisher
- Wiley
- Published
- 2021-09-23
- Volume
- 39
- Issue
- 12
- Pages
- 3225-3230
- ISSN
- 1001-604X (ISSN-L)
- 1614-7065
- OpenAlex
- W3195748181
- Cited by
- 191
- References
- 5
- FWCI
- 10.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, G., Zhang, Z., & Zeng, R. (2021). Photoinduced FeCl3‐Catalyzed Alkyl Aromatics Oxidation toward Degradation of Polystyrene at Room Temperature†. Chinese Journal of Chemistry. https://doi.org/10.1002/cjoc.202100420
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