Issues in the Synthesis of Crystalline Molecular Sieves: Towards the Crystallization of Low Framework‐Density Structures
Abstract
Fundamental and practical interest in crystalline, microporous, molecular sieves is largely a direct consequence of the fact that their bulk properties can be manipulated through variations in atomic structure. This correspondence between the macroscale and the atomic scale is due to the uniformity of these crystalline materials. Control of the atomic structure therefore is of extreme importance, and is the thesis of this Review. Synthesis mechanisms and the parameters that can direct the crystal assembly pathway and the ultimate product formed are discussed and rationalized.
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The way in which OSDAs favor the crystallization of a specific structure is not yet fully understood, despite the large research effort put into it.
“The way in which these OSDAs favor the crystallization of a specific structure is not yet fully understood, despite the large research effort put into it.46,47,95,96”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [95]
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References 92 · Cited by 279
- Authors
- Corma, A., & Davis, M. E.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- California Institute of Technology (US)
- Venue
- ChemPhysChem
- Publisher
- Wiley
- Published
- 2004-03-10
- Volume
- 5
- Issue
- 3
- Pages
- 304-313
- ISSN
- 1439-4235 (ISSN-L)
- 1439-7641
- OpenAlex
- W1989557485
- Cited by
- 279
- References
- 92
- Citations by year
- 2026: 5 · 2025: 6 · 2024: 9 · 2023: 6 · 2022: 9 · 2021: 18 · 2020: 14 · 2019: 8 · 2018: 10 · 2017: 13 · 2016: 13 · 2015: 10 · 2014: 11 · 2013: 17 · 2012: 11
- FWCI
- 11.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemPhysChem (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- microporous materials, synthesis mechanism, crystal assembly, framework density, crystal engineering, zeolites
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