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Heat of Adsorption for Hydrogen in Microporous High‐Surface‐Area Materials
Abstract
Pore size matters: The heat of adsorption for hydrogen is determined over a wide range of surface coverages for activated carbon and several metal–organic frameworks. Heat determination is based on hydrogen adsorption measurements performed at temperatures between 77 and 296 K (see figure, BTC=benzene-1,3,5-tricarboxylate). The materials with smaller cavities show a higher heat of adsorption for hydrogen.
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Citations
Cited by
Templated nanocarbons for energy storage
Nishihara, H., & Kyotani, T. (2012) · Advanced Materials · doi:10.1002/adma.201201715 · Cited by 745
Hydrogen storage in metal–organic frameworks
Collins, D. J., & Zhou, H.-C. (2007) · Journal of Materials Chemistry · doi:10.1039/b702858j · Cited by 720
Sevilla, M., Fuertes, A. B., & Mokaya, R. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00347f · Cited by 481
Metal borohydrides and derivatives – synthesis, structure and properties
Paskevicius, M., Jepsen, L. H., Schouwink, P., Černý, R., Ravnsbæk, D. B., Filinchuk, Y., Dornheim, M., Besenbacher, F., & Jensen, T. R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00705h · Cited by 406
Bhattacharjee, S., Chen, C., & Ahn, W.-S. (2014) · RSC Adv. · doi:10.1039/c4ra11259h · Cited by 301
Metadata
- Authors
- Schmitz, B., Müller, U., Trukhan, N., Schubert, M., Férey, G., & Hirscher, M.
- Venue
- ChemPhysChem
- Publisher
- Wiley
- Published
- 2008-10-17
- Volume
- 9
- Issue
- 15
- Pages
- 2181-2184
- ISSN
- 1439-4235 (ISSN-L)
- 1439-7641
- OpenAlex
- W2100462429
- Cited by
- 182
- References
- 0
- FWCI
- 7.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schmitz, B., Müller, U., Trukhan, N., Schubert, M., Férey, G., & Hirscher, M. (2008). Heat of Adsorption for Hydrogen in Microporous High‐Surface‐Area Materials. ChemPhysChem. https://doi.org/10.1002/cphc.200800463
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
