In Situ Synthesis of NiCoP Nanoparticles Supported on Reduced Graphene Oxide for the Catalytic Hydrolysis of Ammonia Borane
Abstract
Developing highly efficient and stable noble‐metal‐free catalysts toward catalytic hydrolysis of ammonia borane (AB) for hydrogen storage is highly desirable, but still remains challenging. We report a simple and in situ co‐reduction approach to synthesize bimetallic NiCoP nanoparticles (NPs) supported on reduced graphene oxide (rGO). Thanks to the strong electronic interaction between Ni, Co, and P, the as‐synthesized Co 89.8 Ni 10.2 P 11.7/rGO catalyst exhibits superior catalytic performance towards hydrolysis of AB, with the turnover frequency value (TOF) of 18.6 min−1, which is about 2.5 times higher than that of NiCo/rGO.
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Direct carbonization−phosphorization of MOFs provides a feasible scheme to obtain transition metal phosphide nanoparticles anchored within carbon composites.
“The direct carbonization−phosphorization of MOFs to obtain transition metal phosphide nanoparticles anchored within carbon composites has been provided a feasible scheme.35,41−45”
From Bimetallic (Co/Ni) MOF-Derived CoNiP Hierarchically Porous Carbon Monolithic Aerogel for the Hydrolysis of Ammonia Borane (2024) · cites this paper as [45]
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- Authors
- Yang, C., Men, Y., Xu, Y., Liang, L., Cai, P., & Luo, W.
- Affiliations
- Wuhan University (CN)
- Shanghai Yanan High School Maotai Road, Changning District Shanghai 200050 P. R. China
- Corresponding author
- Cai, Ping
- Luo, Wei
- Venue
- ChemPlusChem
- Publisher
- Wiley
- Published
- 2019-04
- Volume
- 84
- Issue
- 4
- Pages
- 382-386
- ISSN
- 2192-6506 (ISSN-L)
- OpenAlex
- W2933896766
- Cited by
- 23
- References
- 0
- Citations by year
- 2026: 1 · 2024: 5 · 2023: 4 · 2022: 1 · 2021: 6 · 2020: 6
- FWCI
- 1.17
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemPlusChem (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21571145)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Physical Sciences › Chemical Engineering › Catalysis › Ammonia Synthesis and Nitrogen Reduction
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- ammonia borane, catalytic hydrolysis, hydrogen storage, reduced graphene oxide, bimetallic catalysts, noble metal-free catalysts, electronic interaction, turnover frequency
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