The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Gold‐Catalyzed Aerobic Oxidation of 5‐Hydroxymethylfurfural in Water at Ambient Temperature
Abstract
The aerobic oxidation of 5‐hydroxymethylfurfural, a versatile biomass‐derived chemical, is examined in water with a titania‐supported gold‐nanoparticle catalyst at ambient temperature (30 °C). The selectivity of the reaction towards 2,5‐furandicarboxylic acid and the intermediate oxidation product 5‐hydroxymethyl‐2‐furancarboxylic acid is found to depend on the amount of added base and the oxygen pressure, suggesting that the reaction proceeds via initial oxidation of the aldehyde moiety followed by oxidation of the hydroxymethyl group of 5‐hydroxymethylfurfural. Under optimized reaction conditions, a 71 % yield of 2,5‐furandicarboxylic acid is obtained at full 5‐hydroxymethylfurfural conversion in the presence of excess base.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Carlini, C., Patrono, P., Galletti, A. M. R., Sbrana, G., & Zima, V. (2005) · Applied Catalysis A: General · doi:10.1016/j.apcata.2005.05.006 · Cited by 178
Ribeiro, M. L., & Schuchardt, U. (2003) · Catalysis Communications · doi:10.1016/s1566-7367(02)00261-3 · Cited by 147
Cited by
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Combined biomass valorization and hydrogen production in a photoelectrochemical cell
Cha, H. G., & Choi, K.-S. (2015) · Nature Chemistry · doi:10.1038/nchem.2194 · Cited by 835
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Catalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Metadata
- Authors
- Gorbanev, Y. Y., Klitgaard, S. K., Woodley, J. M., Christensen, C. H., & Riisager, A.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2009-07-10
- Volume
- 2
- Issue
- 7
- Pages
- 672-675
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2139187943
- Cited by
- 338
- References
- 3
- FWCI
- 13.00
- Type
- journal article
- Language
- en
- Open access
- closed
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