The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Biomass into Chemicals: Aerobic Oxidation of 5‐Hydroxymethyl‐2‐furfural into 2,5‐Furandicarboxylic Acid with Gold Nanoparticle Catalysts
Abstract
5‐hydroxymethyl‐2‐furfural is selectively converted into 2,5‐furandicarboxylic acid (99 mol % yield) in water, under mild conditions (65–130 °C, 10 bar air) with gold nanoparticles supported on nanoparticulate ceria (Au‐CeO 2) and on titania (Au‐TiO 2); the former being more active and selective. A reaction mechanism is established and the rate‐limiting step of the reaction is the alcohol oxidation of 5‐hydroxymethyl‐2‐furancarboxylic acid into 2,5‐furandicarboxylic acid. The effects of pressure, temperature, substrate‐to‐catalyst ratio, and amount of base are studied to find the most suitable reaction conditions. The absence of metal leaching is verified by chemical analysis of the reaction solution and by confirming that the reaction does not occur after catalyst removal by filtration in hot water. Substrate degradation is strongly diminished and the catalyst life increased by performing the reaction in two temperature steps.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Self-citationSupported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Self-citationRibeiro, M. L., & Schuchardt, U. (2003) · Catalysis Communications · doi:10.1016/s1566-7367(02)00261-3 · Cited by 147
Cited by
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Combined biomass valorization and hydrogen production in a photoelectrochemical cell
Cha, H. G., & Choi, K.-S. (2015) · Nature Chemistry · doi:10.1038/nchem.2194 · Cited by 835
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Catalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Recent Advances in the Catalytic Synthesis of 2,5-Furandicarboxylic Acid and Its Derivatives
Zhang, Z., & Deng, K. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01491 · Cited by 641
Metadata
- Authors
- Casanova, O., Iborra, S., & Corma, A.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2009-12-15
- Volume
- 2
- Issue
- 12
- Pages
- 1138-1144
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2112054485
- Cited by
- 524
- References
- 3
- FWCI
- 10.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Casanova, O., Iborra, S., & Corma, A. (2009). Biomass into Chemicals: Aerobic Oxidation of 5‐Hydroxymethyl‐2‐furfural into 2,5‐Furandicarboxylic Acid with Gold Nanoparticle Catalysts. ChemSusChem. https://doi.org/10.1002/cssc.200900137
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