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Transition Metal–Tungsten Bimetallic Catalysts for the Conversion of Cellulose into Ethylene Glycol
Abstract
Tungsten-based bimetallic catalysts (W–M(8,9,10); where M(8,9,10) is Ni, Pd, Pt, Ir, Ru, or Rh) are found to be highly active and selective for the formation of ethylene glycol from cellulose. The cooperation between CC cracking reactions over metallic tungsten and the hydrogenation of unsaturated intermediates over the transition metals M(8,9,10) results in a particularly high selectivity towards ethylene glycol, up to 75 %.
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Cites
Chen, J. G. (1996) · Chemical Reviews · doi:10.1021/cr950232u · Cited by 773
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Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., & Beltramini, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15124j · Cited by 1,420
Ethylene glycol: properties, synthesis, and applications
Yue, H., Zhao, Y., Ma, X., & Gong, J. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15359a · Cited by 1,180
Catalytic conversion of lignocellulosic biomass into chemicals and fuels
Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals
Ruppert, A. M., Weinberg, K., & Palkovits, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105125 · Cited by 836
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De, S., Zhang, J., Luque, R., & Yan, N. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02002j · Cited by 786
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass
Kobayashi, H., & Fukuoka, A. (2013) · Green Chemistry · doi:10.1039/c3gc00060e · Cited by 489
Hydrotreatment of pyrolysis bio-oil: A review
Han, Y., Gholizadeh, M., Tran, C.-C., Kaliaguine, S., Li, C.-Z., Olarte, M., & Garcia-Perez, M. (2019) · Fuel Processing Technology · doi:10.1016/j.fuproc.2019.106140 · Cited by 292
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.04.004 · Cited by 284
Selectivity control for cellulose to diols: dancing on eggs
Zheng, M., Pang, J., Sun, R., Wang, A., & Zhang, T. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03469 · Cited by 210
Self-citationLiu, X., Wang, X., Yao, S., Jiang, Y., Guan, J., & Mu, X. (2014) · RSC Adv. · doi:10.1039/c4ra06466f · Cited by 98
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Metadata
- Authors
- Zheng, M., Wang, A., Ji, N., Pang, J., Wang, X., & Zhang, T.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2010-01-20
- Volume
- 3
- Issue
- 1
- Pages
- 63-66
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2103738125
- Cited by
- 321
- References
- 1
- FWCI
- 9.90
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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