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Cited by 187

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Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic–Inorganic Hybrid Solid Acid Catalyst

Zhang, Zehui, Dong, Kun, Zhao, Zongbao (Kent)·2011·ChemSusChem

Abstract

A clean, facile, and environment‐friendly catalytic method has been developed for the conversion of furfuryl alcohol into alkyl levulinates making use of the novel solid catalyst methylimidazolebutylsulfate phosphotungstate ([MIMBS]3 PW 12 O 40). The solid catalyst is an organic–inorganic hybrid material, which consists of an organic cation and an inorganic anion. A study for optimizing the reaction conditions such as the reaction time, the temperature and the catalyst loading has been performed. Under optimal conditions, a high n‐butyl levulinate yield of up to 93 % is obtained. Furthermore, the kinetics of the reaction pathways and the mechanism for the alcoholysis of furfuryl alcohol are discussed. This method is environmentally benign and economical for the conversion of biomass‐based derivatives into fine chemicals.

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Crossref · 10.1002/cssc.201000231

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Metadata

Authors
Zhang, Z., Dong, K., & Zhao, Z. (.
Venue
ChemSusChem
Publisher
Wiley
Published
2011-01-12
Volume
4
Issue
1
Pages
112-118
ISSN
  • 1864-5631 (ISSN-L)
  • 1864-564X
OpenAlex
W2120972281
Cited by
187
References
1
FWCI
7.84
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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