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Catalytic Air Oxidation of Biomass‐Derived Carbohydrates to Formic Acid
Abstract
An efficient catalytic system for biomass oxidation to form formic acid was developed. The conversion of glucose to formic acid can reach up to 52 % yield within 3 h when catalyzed by 5 mol % of H 5 PV 2 Mo 10 O 40 at only 373 K using air as the oxidant. Furthermore, the heteropolyacid can be used as a bifunctional catalyst in the conversion of cellulose to formic acid (yield=35 %) with air as the oxidant.
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Citations
Cited by
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Catalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system
Singh, A. K., Singh, S., & Kumar, A. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy01276g · Cited by 543
Catalytic Applications of Vanadium: A Mechanistic Perspective
Langeslay, R. R., Kaphan, D. M., Marshall, C. L., Stair, P. C., Sattelberger, A. P., & Delferro, M. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00245 · Cited by 503
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass
Kobayashi, H., & Fukuoka, A. (2013) · Green Chemistry · doi:10.1039/c3gc00060e · Cited by 489
Bulushev, D. A., Zacharska, M., Shlyakhova, E. V., Chuvilin, A. L., Guo, Y., Beloshapkin, S., Okotrub, A. V., & Bulusheva, L. G. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02381 · Cited by 293
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.04.004 · Cited by 284
Zhang, J., Liu, X., Sun, M., Ma, X., & Han, Y. (2012) · ACS Catalysis · doi:10.1021/cs300342k · Cited by 156
Metadata
- Authors
- Li, J., Ding, D., Deng, L., Guo, Q., & Fu, Y.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2012-04-12
- Volume
- 5
- Issue
- 7
- Pages
- 1313-1318
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2059050805
- Cited by
- 171
- References
- 0
- FWCI
- 5.06
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
