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Efficient Water‐Splitting Device Based on a Bismuth Vanadate Photoanode and Thin‐Film Silicon Solar Cells

Han, Lihao, Abdi, Fatwa F., van de Krol, Roel, Liu, Rui, Huang, Zhuangqun, Lewerenz, Hans‐Joachim, Dam, Bernard, Zeman, Miro, Smets, Arno H. M.·2014·ChemSusChem

Abstract

A hybrid photovoltaic/photoelectrochemical (PV/PEC) water‐splitting device with a benchmark solar‐to‐hydrogen conversion efficiency of 5.2 % under simulated air mass (AM) 1.5 illumination is reported. This cell consists of a gradient‐doped tungsten–bismuth vanadate (W:BiVO 4) photoanode and a thin‐film silicon solar cell. The improvement with respect to an earlier cell that also used gradient‐doped W:BiVO 4 has been achieved by simultaneously introducing a textured substrate to enhance light trapping in the BiVO 4 photoanode and further optimization of the W gradient doping profile in the photoanode. Various PV cells have been studied in combination with this BiVO 4 photoanode, such as an amorphous silicon (a‐Si:H) single junction, an a‐Si:H/a‐Si:H double junction, and an a‐Si:H/nanocrystalline silicon (nc‐Si:H) micromorph junction. The highest conversion efficiency, which is also the record efficiency for metal oxide based water‐splitting devices, is reached for a tandem system consisting of the optimized W:BiVO 4 photoanode and the micromorph (a‐Si:H/nc‐Si:H) cell. This record efficiency is attributed to the increased performance of the BiVO 4 photoanode, which is the limiting factor in this hybrid PEC/PV device, as well as better spectral matching between BiVO 4 and the nc‐Si:H cell.

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Metadata

Authors
Han, L., Abdi, F. F., van de Krol, R., Liu, R., Huang, Z., Lewerenz, H., Dam, B., Zeman, M., & Smets, A. H. M.
Venue
ChemSusChem
Publisher
Wiley
Published
2014-08-19
Volume
7
Issue
10
Pages
2832-2838
ISSN
  • 1864-5631 (ISSN-L)
  • 1864-564X
OpenAlex
W2099997863
Cited by
175
References
4
FWCI
6.44
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Efficient Water‐Splitting Device Based on a Bismuth Vanadate Photoanode and Thin‐Film Silicon Solar Cells. https://app.cochat.ai/papers/10.1002/cssc.201402456
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Han, L., Abdi, F. F., van de Krol, R., Liu, R., Huang, Z., Lewerenz, H., Dam, B., Zeman, M., & Smets, A. H. M. (2014). Efficient Water‐Splitting Device Based on a Bismuth Vanadate Photoanode and Thin‐Film Silicon Solar Cells. ChemSusChem. https://doi.org/10.1002/cssc.201402456

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