The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Selective Aerobic Oxidation of HMF to 2,5‐Diformylfuran on Covalent Triazine Frameworks‐Supported Ru Catalysts
Abstract
The selective aerobic oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran has been performed under mild conditions at 80 °C and 20 bar of synthetic air in methyl t‐butyl ether. Ru clusters supported on covalent triazine frameworks (CTFs) allowed excellent selectivity and superior catalytic activity compared to other support materials such as activated carbon, γ‐Al 2 O 3, hydrotalcite, or MgO. CTFs with varying pore size, specific surface area, and N content could be prepared from different monomers. The structural properties of the CTF materials influence the catalytic activity of Ru/CTF significantly in the aerobic oxidation of HMF, which emphasizes the superior activity of mesoporous CTFs. Recycling of the catalysts is challenging, but promising methods to maintain high catalytic activity were developed that facilitate only minor deactivation in five consecutive recycling experiments.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
Eerhart, A. J. J. E., Faaij, A. P. C., & Patel, M. K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02480b · Cited by 666
Carlini, C., Patrono, P., Galletti, A. M. R., Sbrana, G., & Zima, V. (2005) · Applied Catalysis A: General · doi:10.1016/j.apcata.2005.05.006 · Cited by 178
Cited by
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Self-citationCatalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Recent Advances in the Catalytic Synthesis of 2,5-Furandicarboxylic Acid and Its Derivatives
Zhang, Z., & Deng, K. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01491 · Cited by 641
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
Metadata
- Authors
- Artz, J., Mallmann, S., & Palkovits, R.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2015-01-13
- Volume
- 8
- Issue
- 4
- Pages
- 672-679
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2153802348
- Cited by
- 201
- References
- 5
- FWCI
- 12.58
- Type
- journal article
- Language
- en
- Open access
- closed
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