The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Selective Aerobic Oxidation of 5‐HMF into 2,5‐Furandicarboxylic Acid with Pt Catalysts Supported on TiO2‐ and ZrO2‐Based Supports
Open accessAbstract
Pt catalysts prepared over different metallic oxide supports were investigated in the oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) in alkaline aqueous solutions with air, to examine the combined effect of the support and base addition. The base (nature and amount) played a significant role in the degradation or oxidation of HMF. Increasing amounts of the weak NaHCO 3 base improved significantly the overall catalytic activity of Pt/TiO 2 and Pt/ZrO 2 by accelerating the oxidation steps, especially for the aldehyde group. This was highlighted by a proposed kinetic model that gave very good concentration–time fittings. Moreover, the promotion of the catalyst with bismuth yielded a PtBi/TiO 2 catalytic system with improved activity and stability. Y 2 O 3 and La 2 O 3ZrO 2‐supported catalysts exhibited lower activity than Pt/ZrO 2, which suggests no cooperative effect of the weakly basic properties introduced and the homogeneous base. Quantitative oxidation of HMF (0.1 M) and high yields of FDCA (>99 %) were obtained in less than 5 h by using an HMF/Pt molar ratio of 100 and Na 2 CO 3 as a weak base over PtBi/TiO 2 (Bi/Pt=0.22).
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Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Self-citationReplacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
Eerhart, A. J. J. E., Faaij, A. P. C., & Patel, M. K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02480b · Cited by 666
De Souza, R. L., Yu, H., Rataboul, F., & Essayem, N. (2012) · Challenges · doi:10.3390/challe3020212 · Cited by 144
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Cited by
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Catalytic oxidation of carbohydrates into organic acids and furan chemicals
Zhang, Z., & Huber, G. W. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00213k · Cited by 689
Recent Advances in the Catalytic Synthesis of 2,5-Furandicarboxylic Acid and Its Derivatives
Zhang, Z., & Deng, K. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01491 · Cited by 641
Electrocatalytic Oxidation of 5‐(Hydroxymethyl)furfural Using High‐Surface‐Area Nickel Boride
Barwe, S., Weidner, J., Cychy, S., Morales, D. M., Dieckhöfer, S., Hiltrop, D., Masa, J., Muhler, M., & Schuhmann, W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806298 · Cited by 507
Mishra, D. K., Lee, H. J., Kim, J., Lee, H.-S., Cho, J. K., Suh, Y.-W., Yi, Y., & Kim, Y. J. (2017) · Green Chemistry · doi:10.1039/c7gc00027h · Cited by 198
Metadata
- Authors
- Ait Rass, H., Essayem, N., & Besson, M.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2015-03-03
- Volume
- 8
- Issue
- 7
- Pages
- 1206-1217
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2010781899
- Cited by
- 247
- References
- 5
- FWCI
- 12.90
- Type
- journal article
- Language
- en
- Open access
- bronze
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