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Synthesis of a Sulfonated Two‐Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion
Abstract
Because of limited framework stability tolerance, de novo synthesis of sulfonated covalent organic frameworks (COFs) remains challenging and unexplored. Herein, a sulfonated two‐dimensional crystalline COF, termed TFP‐DABA, was synthesized directly from 1,3,5‐triformylphloroglucinol and 2,5‐diaminobenzenesulfonic acid through a previously reported Schiff base condensation reaction, followed by irreversible enol‐to‐keto tautomerization, which strengthened its structural stability. TFP‐DABA is a highly efficient solid acid catalyst for fructose conversion with remarkable yields (97 % for 5‐hydroxymethylfurfural and 65 % for 2,5‐diformylfuran), good chemoselectivity, and good recyclability. The present study sheds light on the de novo synthesis of sulfonated COFs as novel solid acid catalysts for biobased chemical conversion.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Cited by
Metal–organic and covalent organic frameworks as single-site catalysts
Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., et al. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00033b · Cited by 1,077
Opportunities of Covalent Organic Frameworks for Advanced Applications
Song, Y., Sun, Q., Aguila, B., & Ma, S. (2019) · Advanced Science · doi:10.1002/advs.201801410 · Cited by 586
Continuous Flow Upgrading of Selected C2–C6Platform Chemicals Derived from Biomass
Gérardy, R., Debecker, D. P., Estager, J., Luis, P., & Monbaliu, J.-C. M. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00846 · Cited by 398
Metadata
- Authors
- Peng, Y., Hu, Z., Gao, Y., Yuan, D., Kang, Z., Qian, Y., Yan, N., & Zhao, D.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2015-09-03
- Volume
- 8
- Issue
- 19
- Pages
- 3208-3212
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2144613836
- Cited by
- 241
- References
- 2
- FWCI
- 6.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Peng, Y., Hu, Z., Gao, Y., Yuan, D., Kang, Z., Qian, Y., Yan, N., & Zhao, D. (2015). Synthesis of a Sulfonated Two‐Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion. ChemSusChem. https://doi.org/10.1002/cssc.201500755
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