The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Hierarchical Nickel–Cobalt‐Based Transition Metal Oxide Catalysts for the Electrochemical Conversion of Biomass into Valuable Chemicals
Abstract
The upgrading of biomass into sustainable and valuable fine chemicals is an alternative to the use of state‐of‐the‐art petrochemicals. The conversion of 5‐hydroxymethylfurfural (HMF) biomass derivative into 2,5‐furandicarboxylic acid (FDCA) has been recognized as an economical and green approach to replace the current polyethylene terephthalate based plastic industry. However, this reaction mostly relies on noble‐metal‐based catalysts for the sluggish aerobic oxidation of alcohol groups. In this work, we report a series of hierarchical Ni−Co‐based transition metal oxide catalysts for HMF oxidation by electrocatalysis. Comprehensive material characterization and electrochemical evaluation have been performed. A 90 % FDCA yield, nearly 100 % Faradaic efficiency, and robust stability were achieved for NiCo 2 O 4 nanowires. As non‐precious‐metal catalysts, Ni−Co‐based transition metal oxides may open up new potential materials for highly efficient electrochemical biomass upgrading.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
Eerhart, A. J. J. E., Faaij, A. P. C., & Patel, M. K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02480b · Cited by 666
Cited by
Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Zhang, N., Zou, Y., Tao, L., Chen, W., Zhou, L., Liu, Z., Zhou, B., Huang, G., Lin, H., & Wang, S. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908722 · Cited by 523
Lu, Y., Liu, T., Huang, Y.-C., Zhou, L., Li, Y., Chen, W., Yang, L., Zhou, B., Wu, Y., Kong, Z., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c00174 · Cited by 282
Circumventing Challenges: Design of Anodic Electrocatalysts for Hybrid Water Electrolysis Systems
Wang, H., Sun, M., Ren, J., & Yuan, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203568 · Cited by 183
Xu, P., Bao, Z., Zhao, Y., Zheng, L., Lv, Z., Shi, X., Wang, H., Fang, X., & Zheng, H. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202303557 · Cited by 128
Metadata
- Authors
- Gao, L., Bao, Y., Gan, S., Sun, Z., Song, Z., Han, D., Li, F., & Niu, L.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2018-07-12
- Volume
- 11
- Issue
- 15
- Pages
- 2547-2553
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2805268646
- Cited by
- 169
- References
- 3
- FWCI
- 5.47
- Type
- journal article
- Language
- en
- Open access
- closed
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