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Developing Remote Metal Binding Sites in Heteropolymolybdates
Open accessAbstract
Anderson‐type polyoxomolybdates [MMo 6 O 18{(OCH 2)3 CNH 2}2]3− (M = Mn III, Fe III) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = Ni II or Zn II are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese‐containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono‐ and bidentate binding sites for metal cations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Cited by
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
Dolbecq, A., Dumas, E., Mayer, C. R., & Mialane, P. (2010) · Chemical Reviews · doi:10.1021/cr1000578 · Cited by 1,755
Anyushin, A. V., Kondinski, A., & Parac-Vogt, T. N. (2020) · Chemical Society Reviews · doi:10.1039/c8cs00854j · Cited by 444
Metadata
- Authors
- Marcoux, P. R., Hasenknopf, B., Vaissermann, J., & Gouzerh, P.
- Venue
- European Journal of Inorganic Chemistry
- Publisher
- Wiley
- Published
- 2003-06-24
- Volume
- 2003
- Issue
- 13
- Pages
- 2406-2412
- ISSN
- 1099-0682 (ISSN-L)
- 1434-1948
- OpenAlex
- W1963913767
- Cited by
- 196
- References
- 1
- FWCI
- 1.27
- Type
- journal article
- Language
- en
- Open access
- green
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- Marcoux, P. R., Hasenknopf, B., Vaissermann, J., & Gouzerh, P. (2003). Developing Remote Metal Binding Sites in Heteropolymolybdates. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.200200677
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