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Gold‐Catalyzed Hydroamination of C–C Multiple Bonds
Abstract
The development of general and efficient methods for the addition of an N–H bond across a C–C multiple bond (hydroamination) represents a significant challenge in both organic synthesis and homogeneous catalysis. Although a diverse range of transition‐metal complexes have been employed as catalysts for hydroamination, examples of gold‐catalyzed hydroamination were exceedingly rare prior to 2001. However, over the past five years gold complexes have been applied as catalysts for a number of selective organic transformations including the hydroamination of unactivated alkenes, alkynes, allenes, and 1,3‐dienes. This Microreview provides a brief overview of the gold‐catalyzed hydroamination of C–C multiple bonds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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Citations
Cited by
Gold-Catalyzed Organic Reactions
Hashmi, A. S. K. (2007) · Chemical Reviews · doi:10.1021/cr000436x · Cited by 3,271
Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
Müller, T. E., Hultzsch, K. C., Yus, M., Foubelo, F., & Tada, M. (2008) · Chemical Reviews · doi:10.1021/cr0306788 · Cited by 2,090
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Chemoselectivity and the Curious Reactivity Preferences of Functional Groups
Afagh, N. A., & Yudin, A. K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200901317 · Cited by 320
Metadata
- Authors
- Widenhoefer, R. A., & Han, X.
- Venue
- European Journal of Organic Chemistry
- Publisher
- Wiley
- Published
- 2006-09-20
- Volume
- 2006
- Issue
- 20
- Pages
- 4555-4563
- ISSN
- 1099-0690 (ISSN-L)
- 1434-193X
- OpenAlex
- W2000911567
- Cited by
- 508
- References
- 0
- FWCI
- 29.91
- Type
- journal article
- Language
- en
- Open access
- closed
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