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Hydrogen Evolution from Water by Visible Light, a Homogeneous Three Component Test System for Redox Catalysis
Open accessAbstract
Irradiation by visible light of a neutral aqueous solution containing Ru (bipy) as a sensitizer, methylviologen (MV+2) as an electron acceptor and triethanolamine or cysteine as an electron donor leads to the formation of stable methylviologen radical cation (MV+). The kinetics and mechanism of the photoinduced reactions occurring in such a system were explored by laser photolysis technique. In the presence of Adams catalyst MV+ is reoxidized by water under simultaneous evolution of hydrogen. Optimum conditions for the water reduction under continuous illumination are elaborated and implications for an energy conversion system discussed.
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Cites
Creutz, C., & Sutin, N. (1975) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.72.8.2858 · Cited by 294
Quenching and sensitization processes of coordination compounds
Balzani, V., Moggi, L., Manfrin, M. F., Bolletta, F., & Laurence, G. S. (1975) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(00)82070-6 · Cited by 201
Electron transfer quenching of excited states of metal complexes
Young, R. C., Meyer, T. J., & Whitten, D. G. (1976) · Journal of the American Chemical Society · doi:10.1021/ja00417a073 · Cited by 104
Cited by
Visible light photocatalysis as a greener approach to photochemical synthesis
Yoon, T. P., Ischay, M. A., & Du, J. (2010) · Nature Chemistry · doi:10.1038/nchem.687 · Cited by 2,657
Artificial photosynthesis: water cleavage into hydrogen and oxygen by visible light
Graetzel, M. (1981) · Accounts of Chemical Research · doi:10.1021/ar00072a003 · Cited by 819
Recent Developments in the Application of Phosphorescent Iridium(III) Complex Systems
Ulbricht, C., Beyer, B., Friebe, C., Winter, A., & Schubert, U. S. (2009) · Advanced Materials · doi:10.1002/adma.200803537 · Cited by 746
You, Y., & Nam, W. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35171d · Cited by 668
Sacrificial electron donor reagents for solar fuel production
Pellegrin, Y., & Odobel, F. (2016) · Comptes Rendus. Chimie · doi:10.1016/j.crci.2015.11.026 · Cited by 561
Metadata
- Authors
- Kalyanasundaram, K., Kiwi, J., & Grätzel, M.
- Venue
- Helvetica Chimica Acta
- Publisher
- Wiley
- Published
- 1978-11
- Volume
- 61
- Issue
- 7
- Pages
- 2720-2730
- ISSN
- 0018-019X (ISSN-L)
- 1522-2675
- OpenAlex
- W2160316077
- Cited by
- 580
- References
- 3
- FWCI
- 47.20
- Type
- journal article
- Language
- en
- Open access
- green
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- Kalyanasundaram, K., Kiwi, J., & Grätzel, M. (1978). Hydrogen Evolution from Water by Visible Light, a Homogeneous Three Component Test System for Redox Catalysis. Helvetica Chimica Acta. https://doi.org/10.1002/hlca.19780610740
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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