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Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family
Abstract
The photophysical and electron transfer properties of the lowest excited state of nine ruthenium (polypyridine) complexes have been characterized. The complexes studied are Ru (bpy)3‐n (LL)2+n, where n varies from 0 to 3, and LL is 4, 4′‐di‐t‐butyl‐2,2′‐bipyridine (DTB‐bpy), 3, 3′‐dimethyl‐2, 2′‐bipyridine (DM‐bpy), or a 2, 2′‐diquinolyl derivative (DMCH). The results obtained show that the Ru (bpy)2(DMCH)2+ complex is expected to be a more efficient mediator than Ru (bpy)2+3 in the water‐splitting reaction by solar energy.
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Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
Juris, A., Balzani, V., Barigelletti, F., Campagna, S., Belser, P., & von Zelewsky, A. (1988) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(88)80032-8 · Cited by 4,862
Self-citationTay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Metal-complex chromophores for solar hydrogen generation
Yuan, Y.-J., Yu, Z.-T., Chen, D.-Q., & Zou, Z.-G. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00436a · Cited by 423
Effect of delocalization and rigidity in the acceptor ligand on MLCT excited-state decay
Treadway, J. A., Loeb, B., Lopez, R., Anderson, P. A., Keene, F. R., & Meyer, T. J. (1996) · Inorganic Chemistry · doi:10.1021/ic950961s · Cited by 249
Metadata
- Authors
- Juris, A., Balzani, V., Belser, P., & von Zelewsky, A.
- Venue
- Helvetica Chimica Acta
- Publisher
- Wiley
- Published
- 1981-11-04
- Volume
- 64
- Issue
- 7
- Pages
- 2175-2182
- ISSN
- 0018-019X (ISSN-L)
- 1522-2675
- OpenAlex
- W2021911433
- Cited by
- 215
- References
- 0
- FWCI
- 4.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Juris, A., Balzani, V., Belser, P., & von Zelewsky, A. (1981). Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family. Helvetica Chimica Acta. https://doi.org/10.1002/hlca.19810640723
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