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Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family

Juris, Alberto, Balzani, Vincenzo, Belser, Peter, von Zelewsky, Alex·1981·Helvetica Chimica Acta

Abstract

The photophysical and electron transfer properties of the lowest excited state of nine ruthenium (polypyridine) complexes have been characterized. The complexes studied are Ru (bpy)3‐n (LL)2+n, where n varies from 0 to 3, and LL is 4, 4′‐di‐t‐butyl‐2,2′‐bipyridine (DTB‐bpy), 3, 3′‐dimethyl‐2, 2′‐bipyridine (DM‐bpy), or a 2, 2′‐diquinolyl derivative (DMCH). The results obtained show that the Ru (bpy)2(DMCH)2+ complex is expected to be a more efficient mediator than Ru (bpy)2+3 in the water‐splitting reaction by solar energy.

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Metadata

Authors
Juris, A., Balzani, V., Belser, P., & von Zelewsky, A.
Venue
Helvetica Chimica Acta
Publisher
Wiley
Published
1981-11-04
Volume
64
Issue
7
Pages
2175-2182
ISSN
  • 0018-019X (ISSN-L)
  • 1522-2675
OpenAlex
W2021911433
Cited by
215
References
0
FWCI
4.27
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family. https://app.cochat.ai/papers/10.1002/hlca.19810640723
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Juris, A., Balzani, V., Belser, P., & von Zelewsky, A. (1981). Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family. Helvetica Chimica Acta. https://doi.org/10.1002/hlca.19810640723

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